Citation: Cao Meng, Wang Zhenxi, Zhang Jian, Xu Sheng, Zhang Shangxi, Liu Yang, Dai Xin, Jiang Xinde, Wu Jinhui. Synthesis of Two Heterogeneous Pd Catalysts Based on Nano Silica and MCM-41 and Their Application in Suzuki Reaction[J]. Chemistry, ;2019, 82(4): 340-349. shu

Synthesis of Two Heterogeneous Pd Catalysts Based on Nano Silica and MCM-41 and Their Application in Suzuki Reaction

College of Sciences, Nanchang Institute of Technology, Nanchang 330099

Corresponding author: Wang Zhenxi, wangzhenxi1978@126.com
Received Date: 8 August 2018
Accepted Date: 5 January 2019

Figures(9)

Palladium compounds containing diphosphine ligand with N atom were immobilized on the surface of nano silica and MCM-41 respectively. The resulting two novel heterogeneous Pd catalysts SiO₂@PNPPdCl₂ (1) and MCM-41@PNPPdCl₂(2) were fully characterized by SEM (EDX), TEM (SAED), XRD, FT-IR, ICP-Ms and TGA. Microstructure tests showed that the two kinds of nanoparticles have completely different structures, 1 has an irregular sphere structure and 2 has a honeycomb structure. The catalytic performance of nanoparticles 1 and 2 under mild conditions with EtOH/H₂O (v/v=3/2) as solvent in Suzuki coupling reaction was further studied. The two catalysts had good group tolerance, and their average yields in four cycles were 81% (1) and 89% (2) respectively. Their catalytic properties are also slightly different. The catalytic rate of catalyst 1 is much faster than that of 2, while catalyst 2 has better recycling performance.
- Nano Silica,
- MCM-41,
- Surface Modification,
- Heterogeneous catalysis,
- Suzuki Reaction
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