Citation: Zhao Lingyu, Wang Jiaojiao, Gao Wenhui. Preparation of Cyhalothrin Molecularly Imprinted Solid-Phase Extraction Membrane and Its Application in Food Detection[J]. Chemistry, ;2019, 82(1): 80-86. shu

Preparation of Cyhalothrin Molecularly Imprinted Solid-Phase Extraction Membrane and Its Application in Food Detection

College of Biological Science and Engineering, Hebei University of Science and Technology; Center for Fermentation Engineering of Hebei Province, Shijiazhuang 050000

Corresponding author: Gao Wenhui, wenuigao@126.com
Received Date: 28 June 2018
Accepted Date: 26 September 2018

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A molecularly imprinted solid phase extraction membrane with high selectivity to pyrethroid was prepared by in situ polymerization using cyhalothrin as template molecule, ethylene glycol dimethacrylate as the cross linking agent and acetonitrile as porogenic agent, and the performance and application of as-prepared molecularly imprinted membrane were investigated. Ultraviolet spectroscopy was used to study the selection of functional monomer and the concentration ratio of functional monomer to template molecule. This molecularly imprinted membrane was used to enrich and cleanse pyrethrin pesticide residues in samples. The results showed that the membrane had strong specific adsorption and enrichment capacity for pyrethrin pesticides. The detection limits were 0.01μg/mL for cyhalothrin and bifenthrin, 0.05μg/mL for tetramethrin, beta cypermethrin, dimefluthrin and fenvalerate. The average recoveries of the spiked samples were between 83.4% and 95.9%, the relative standard deviations were 1.45%~3.76% (n=5). The method is simple, sensitive, accurate and reliable.
- Cyhalothrin,
- Pyrethrin pesticide,
- Molecularly imprinted solid phase extraction membrane
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