Citation: WANG Chun-sheng, WANG Yi-shuang, CHEN Ming-qiang, TANG Zhi-yuan, ZHANG Han, YANG Zhong-lian, WANG Jun. Effect of Ce modified Co/SEP catalyst on hydrogen production via ethanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(5): 558-565. shu

Effect of Ce modified Co/SEP catalyst on hydrogen production via ethanol steam reforming

1.
School of Chemical Engineering, Anhui University of Science & Technology, Huainan 232001, China
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School of Energy and Safety, Anhui University of Science & Technology, Huainan 232001, China

Corresponding author: WANG Chun-sheng, wangchunshengaust@163.com CHEN Ming-qiang, mqchen@aust.edu.cn
Received Date: 14 January 2019
Revised Date: 16 February 2019

Fund Project: the National Natural Science Foundation of China 51876001The project was supported by the National Natural Science Foundation of China (51876001 and 21376007), National Key Technology R&D Program of the Ministry of Science and Technology of China (2014BAD02B03) and China Postdoctoral Science Foundation (2018M642505)the National Natural Science Foundation of China 21376007China Postdoctoral Science Foundation 2018M642505National Key Technology R&D Program of the Ministry of Science and Technology of China 2014BAD02B03

Figures(7)

Co/SEP and Co-Ce/SEP catalysts were prepared by chemical precipitation method with sepiolite (SEP) as support. X-ray diffraction (XRD), H₂-programmed reduction (H₂-TPR) and transmission electron microscopy (TEM) were used to characterize the catalysts. It is proved that the addition of Ce significantly improved the dispersion and reducibility of the catalyst. The effects of Ce addition, reaction time, reaction temperature and steam/carbon (S/C) ratio on hydrogen production were investigated. The results show that the ethanol conversion and hydrogen production of Co-Ce/SEP are the highest values, 85% and 65%, respectively, when the WHSV is 20.5 h^-1, the S/C ratio is 3 and the reaction temperature is 600℃. Meanwhile, the addition of Ce can make Co-Ce/SEP possess superior activity and stability.
- catalytic steam reforming,
- hydrogen production via ethanol,
- sepiolite,
- cobalt based catalyst
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