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Citation: Di Yanqing, Di Youying, Liu Yongliang, Zhou Chunsheng, Chen Fengying, Yang Zhiting. Synthesis, Crystal Structure and Properties of Mn(Ⅱ) Coordination Compound Based on Aromatic Acyl Hydrazone Ligand[J]. Chemistry, ;2017, 80(8): 760-764. shu

Synthesis, Crystal Structure and Properties of Mn(Ⅱ) Coordination Compound Based on Aromatic Acyl Hydrazone Ligand

College of Chemical Engineering and Modern Materials, Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, Shangluo University, Shangluo 726000

Corresponding author: Zhou Chunsheng, slzhoucs@126.com
Received Date: 21 January 2017
Accepted Date: 3 March 2017

Figures(9)

Mn(Ⅱ) coordination compound, Mn(o-PAMH)(H₂O)₂ (o-PAMH=2-oxo-propionic acid 2-methoxy benzoyl hydrazone), has been synthesized using solution diffusion method at room temperature. The crystal structure and characteristics of the coordination compound were determined by X-ray crystallography and thermogravimetric analysis (TGA). Single-crystal X-ray diffraction analysis revealed that the complex was crystallized in the monoclinic space group P-1 with unit cell parameters a=0.7925(2) nm, b=1.0529(3) nm, c=1.1069(4) nm, α=68.142(6)°, β=69.053(4)°, γ=71.292(4)°, V=0.7816(4) nm³, and Z=1. The asymmetric unit contains only one crystallographically independent manganese ion, which is seven-coordinated and exhibits slightly distorted pentagonal bipyramid geometry. The complex displays a dinuclear and zero dimensional structure. The ultraviolet and fluorescent properties of the complex have been investigated.
- Manganese complexe,
- Crystal structure,
- Spectral properties,
- X ray crystallography,
- Thermo-gravimetric analysis(TGA)
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