Citation: CHEN Yan-guang, KANG Wei, HAN Hong-jing, ZHANG Ya-nan, WANG Hai-ying, XU Ting-ting, YANG Xiu-qi, SONG Hua. Regulation of the crystal growth of NaP zeolite with organic steric hindrance agents[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(10): 1251-1259. shu

Regulation of the crystal growth of NaP zeolite with organic steric hindrance agents

CHEN Yan-guang ^1,2,, ,
KANG Wei ^1,2 ,
HAN Hong-jing ^1,2 ,
ZHANG Ya-nan ^1,2 ,
WANG Hai-ying ^1,2 ,
XU Ting-ting ³ ,
YANG Xiu-qi ^1,2 ,
SONG Hua ^1,2

1.
College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Heilongjiang Provincial Key Laboratory of Oil and Gas Chemical Technology, Daqing 163318, China
3.
Daqing Petrochemical Research Center of CNPC, Daqing 163714, China

Corresponding author: CHEN Yan-guang, ygchen79310@126.com
Received Date: 17 April 2017
Revised Date: 7 July 2017

Fund Project: The project was supported by the National Natural Science Foundation of China 51674089the Postgraduate Innovative Resative Research Projects of Northeast Petroleum University YJSCX2015-022NEPUthe Program for New Century Excellent Talent in University of Heilongjiang Province 1254-NCET-004The project was supported by the National Natural Science Foundation of China (51674089), the Program for New Century Excellent Talent in University of Heilongjiang Province (1254-NCET-004), Postdoctoral Scientific Research Developmental Fund (LHB-Q16037), the Postgraduate Innovative Resative Research Projects of Northeast Petroleum University (YJSCX2017-014NEPU and YJSCX2015-022NEPU)Postdoctoral Scientific Research Developmental Fund LHB-Q16037the Postgraduate Innovative Resative Research Projects of Northeast Petroleum University YJSCX2017-014NEPU

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With sodium silicate and sodium aluminate extracted from fly ash as the raw materials, NaP zeolite was prepared by hydrothermal synthesis method; the synthesis parameters such as crystallization time, temperature and the ratio of silicon/H₂O were optimized via orthogonal tests. The method to regulate the crystal growth process was proposed through controlling the steric hindrance effect. The NaP zeolite was characterized by XRD, FT-IR, SEM and N₂ sorption; the effect of steric hindrance on the crystal phase and grain size was investigated. The results show that the morphology and grain size of NaP zeolite can be effectively regulated by introducing steric hindrance agents into the hydrothermal reaction system. The strength of steric hindrance effect of various agents follows the order of ring structure > linear structure, long chain structure > short chain structure. The adsorption test suggests that removal rate of Zn²⁺ exceeds 99.8% for NaP zeolite under the optimal adsorption conditions.
- fly ash,
- steric hindrance regulation,
- NaP zeolite,
- Zn²⁺,
- adsorption performance
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1.
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