Citation: OUYANG Qian, YANG Ni, YAO Jing-wen, HUANG Jin, ZHANG Yi, LIU Xue-jun. Research on the catalytic performance of supported Pt catalyst for hydrodeoxygenation of biodiesel[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(10): 1202-1209. shu

Research on the catalytic performance of supported Pt catalyst for hydrodeoxygenation of biodiesel

OUYANG Qian ¹ ,
YANG Ni ¹ ,
YAO Jing-wen ¹ ,
HUANG Jin ² ,
ZHANG Yi ¹ ,
LIU Xue-jun ^1,,

1.
Zhejiang Provincial Key Laboratory of Biofuel Utilization Technology, Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, School of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
2.
Zhejiang Pharmaceutical Co., Ltd. Changhai Biological Division, Shaoxing 312000, China

Corresponding author: LIU Xue-jun, zjutjjb@163.com
Received Date: 17 May 2018
Revised Date: 22 July 2018

Figures(6)

The Pt/Al₂O₃, Pt/Al₂O₃-ZSM-5 and Pt/ZSM-5 catalysts were prepared and characterized by XRD, BET, SEM and NH₃-TPD. The effects of crystal structure, acidity, pore size distribution and external shape of the three catalysts on the hydrodeoxygenation of fatty acid methyl esters were investigated under different reaction conditions. The results show that the Brønsted acidic sites and proportion of mesoporous volume were critical for the hydrodeoxygenation of fatty acid methyl esters. The Brønsted acidic site plays a major role in the C-O bond breakage of deoxygenation reaction, the mesopores improved the mass transfer efficiency of the entire reaction and avoided cracking of C_12-18 long chain alkanes. The hydrodeoxygenation activity of the three catalysts were as follow:Pt/Al₂O₃-ZSM-5>Pt/Al₂O₃>Pt/ZSM-5. The optimal reaction conditions were as follow:t=350 ℃, p=2 MPa, H₂/oil=1000, WHSV=0.5 h^-1. Under the optimal reaction conditions, the fatty acid methyl ester conversion of Pt/Al₂O₃-ZSM-5 was 99.4%, and the liquid yield of the target product was 86.8%.
- Pt/Al₂O₃-ZSM-5,
- hydrodeoxygenation,
- Brønsted acid,
- mesoporous volume,
- long chain alkanes
1. [1]
  ZHAO X H, WEI L, CHENG S Y, JULSON J. Review of heterogeneous catalysts for catalytically upgrading vegetable oils into hydrocarbon biofuels[J]. Catalysts, 2017,7(3):83-107.
2. [2]
  ZHANG S, YAN Y, LI T Z. Upgrading of liquid fuel from the pyrolysis of biomass[J]. Bioresource Technol, 2005,96(5):545-550. doi: 10.1016/j.biortech.2004.06.015
3. [3]
  HUBER G W, IBORRA S, CORMA A. Synthesis of transportation fuels from biomass:Chemistry, catalysts, and engineering[J]. Chem Rev, 2006,106(9):4044-4098. doi: 10.1021/cr068360d
4. [4]
  SHI Y C, XING E H, WU K J, WANG J L, YANG M D, WU Y L. Recent progress on upgrading of bio-oil to hydrocarbons over metal/zeolite bifunctional catalysts[J]. Catal Sci Technol, 2017,7(12):2385-2415. doi: 10.1039/C7CY00574A
5. [5]
  DICKERSON T, SORIA J. Catalytic fast pyrolysis:A Review[J]. Energies, 2013,6(1):514-538. doi: 10.3390/en6010514
6. [6]
  YANG Xiao-dong, WANG Xin-miao, GAO Shan-bin, WANG An-jie. Hydrodesulfurization performances of Pd catalysts supported on ZSM-5/MCM-41 composite zeolite[J]. Acta Chim Sin, 2017,75(5):479-484.
7. [7]
  ZUO Hua-liang, LIU Qi-ying, WANG Tie-jun, SHI Na, LIU Jian-guo, MA Long-long. Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel[J]. J Fuel Chem Technol, 2012,40(9):1067-1073. doi: 10.3969/j.issn.0253-2409.2012.09.007
8. [8]
  ECHEANDIA S, PAWELEC B, BARRIO V L, ARIAS P L, CAMBRA J F, LORICERA C V, FIERRO J L G. Enhancement of phenol hydrodeoxygenation over Pd catalysts supported on mixed HY zeolite and Al₂O₃. An approach to O-removal from bio-oils[J]. Fuel, 2014,117(1):1061-1073.
9. [9]
  JI Y J, YANG H H, YAN W. Strategies to enhance the catalytic performance of ZSM-5 zeolite in hydrocarbon cracking:A Review[J]. Catalysts, 2017,7(12):367-397. doi: 10.3390/catal7120367
10. [10]
  CHENG S Y, WEI L, JULSON J, MUTHUKUMARAPPAN K, KHAREL P R. Upgrading pyrolysis bio-oil to hydrocarbon enriched biofuel over bifunctional Fe-Ni/HZSM-5 catalyst in supercritical methanol[J]. Fuel Process Technol, 2017,167(12):117-126.
11. [11]
  LIU J N, XIANG M, WU D F. Enhanced phenol hydrodeoxygenation over a Ni catalyst supported on a mixed mesoporous ZSM-5 zeolite and Al₂O₃[J]. Catal Lett, 2017,147(10):2498-2507. doi: 10.1007/s10562-017-2161-y
12. [12]
  KANG J C, CHENG K, ZHANG L, ZHANG Q H, DING J S, HUA W Q, LOU Y C, ZHAI Q G, WANG Y. Mesoporous zeolite-supported ruthenium nanoparticles as highly selective Fischer-Tropsch catalysts for the production of C_5-11 isoparaffins[J]. Angew Chem, 2011,123(22):5306-5309. doi: 10.1002/ange.v123.22
13. [13]
  CHEN N, GONG S F, SHIRAI H, WATANABE T, QIAN E W. Effects of Si/Al ratio and Pt loading on Pt/SAPO-11 catalysts in hydroconversion of Jatropha oil[J]. Appl Catal A:Gen, 2013,466(36):105-115.
14. [14]
  SANKARANARAYANAN T M, BERENGUER A, OCHOA-HERNáNDEZ C, MORENO I, JANA P, CORONADO J M, SERRANO D P, PIZARRO P. Hydrodeoxygenation of anisole as bio-oil model compound over supported Ni and Co catalysts:Effect of metal and support properties[J]. Catal Today, 2015,243(8):163-172.
15. [15]
  CHEN N, WANGN N N, REN Y X, TOMINAGA H, QIAN E W. Effect of surface modification with silica on the structure and activity of Pt/ZSM-22@SiO₂, catalysts in hydrodeoxygenation of methyl palmitate[J]. J Catal, 2017,345:124-134. doi: 10.1016/j.jcat.2016.09.005
16. [16]
  SRIFA A, FAUNGNAWAKIJ K, ITTHIBENCHAPONG V, VIRIYA-EMPIKUL N, CHARINPANITKUL T, ASSABUMRUNGRAT S. Production of bio-hydrogenated diesel by catalytic hydrotreating of palm oil over NiMoS₂/γ-Al₂O₃ catalyst[J]. Bioresouce Technol, 2014,158(X):81-90.
1. [1]
  Runze Liu , Yankai Bian , Weili Dai . Qualitative and quantitative analysis of Brønsted and Lewis acid sites in zeolites: A combined probe-assisted 1H MAS NMR and NH3-TPD investigation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100250-100250. doi: 10.1016/j.cjsc.2024.100250
2. [2]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
3. [3]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
4. [4]
  Jiajun Lu , Zhehui Liao , Tongxiang Cao , Shifa Zhu . Synergistic Brønsted/Lewis acid catalyzed atroposelective synthesis of aryl-β-naphthol. Chinese Chemical Letters, 2025, 36(1): 109842-. doi: 10.1016/j.cclet.2024.109842
5. [5]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
6. [6]
  Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
7. [7]
  Le Han , Zhou Yuan , Bohan Li , Yuchi Zhang , Lin Yang , Yan Xu . Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation. Chinese Chemical Letters, 2025, 36(6): 110349-. doi: 10.1016/j.cclet.2024.110349
8. [8]
  Junjie Duan , Dan Chen , Long Chen , Shuying Li , Ting Chen , Dong Wang . 2D hexagonal tessellations sustained by Br···Br/H contacts: From regular to semiregular to k-uniform tilings. Chinese Chemical Letters, 2025, 36(3): 110445-. doi: 10.1016/j.cclet.2024.110445
9. [9]
  Chao Liu , Huan Yu , Jiaming Li , Xi Yu , Zhuangzhi Yu , Yuxi Song , Feng Zhang , Qinfang Zhang , Zhigang Zou . Facile synthesis of hierarchical Ti₃C₂/Bi₁₂O₁₇Br₂ Schottky heterojunction with photothermal effect for solar-driven antibiotics photodegradation. Acta Physico-Chimica Sinica, 2025, 41(7): 100075-. doi: 10.1016/j.actphy.2025.100075
10. [10]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
11. [11]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Shanyuan Bi , Jin Zhang , Dengchao Peng , Danhong Cheng , Jianping Zhang , Lupeng Han , Dengsong Zhang . Improved N₂ selectivity for low-temperature NO_x reduction over etched ZSM-5 supported MnCe oxide catalysts. Chinese Chemical Letters, 2025, 36(5): 110295-. doi: 10.1016/j.cclet.2024.110295
14. [14]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
15. [15]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
16. [16]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
17. [17]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
18. [18]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
19. [19]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
20. [20]
  Peng Li , Yuanying Cui , Zhongliao Wang , Graham Dawson , Chunfeng Shao , Kai Dai . Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100065-. doi: 10.1016/j.actphy.2025.100065

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1327)
HTML views(302)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142