Citation: KONG Ting-ting, DONG Yi-fan, ZHANG Ying-ping, ZHANG Ya-gang, ZHOU An-ning. Preparation of hydrotalcite-like Ti/Li/Al-LDHs and its performance in CO₂ adsorption[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(8): 1017-1024. shu

Preparation of hydrotalcite-like Ti/Li/Al-LDHs and its performance in CO₂ adsorption

College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China

Corresponding author: ZHOU An-ning, psu564@139.com
Received Date: 7 April 2016
Revised Date: 18 June 2016

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A series of hydrotalcite-like Ti/Li/Al-LDHs materials were prepared by co-precipitation method and characterized by atomic absorption spectrophotometer (AAS), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal gravimetric analysis (TG) and Fourier transform infrared (FT-IR); the influence of metal composition and calcination temperature on the structure, morphology and CO₂ adsorption capacity of Ti/Li/Al-LDHs was investigated. The results showed that Ti₁Li₃Al₄-LDHs obtained with a Ti/Li/Al ratio of 1:3:4 displays the highest crystallinity and regular morphology, whereas Ti₁Li₃Al₂-LDHs₃₀₀ prepared with a Ti/Li/Al ratio of 1:3:2 and calcined at 300℃ exhibits the best adsorption performance towards CO₂. The CO₂ adsorption capacity over Ti₁Li₃Al₂-LDHs₃₀₀ reaches 53.5mg/g; in addition, the adsorption capacity is only decreased by 2.4% after adsorption for 10 cycles.
- layered double hydroxides,
- Ti/Li/Al-LDHs,
- metal element,
- calcination,
- carbon dioxide,
- adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of hydrotalcite-like Ti/Li/Al-LDHs and its performance in CO2 adsorption

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Preparation of hydrotalcite-like Ti/Li/Al-LDHs and its performance in CO₂ adsorption