Citation: LIU Meng-jie, DING Wei, DAI Yong-chuan, ZHAO Yu-zhu, ZHAO Yue, HAO Yuan-chuan. Preparation of Au/β-Mo₂C catalyst with high thermal stability and its performance in the reverse water-gas shift[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(3): 349-356. shu

Preparation of Au/β-Mo₂C catalyst with high thermal stability and its performance in the reverse water-gas shift

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
No.3 Petrochemical Refinery of Fushun Petrochemical Co. Ltd. CNPC, Fushun 113004, China
3.
PetroChina Daqing Oilfield Co., Ltd., Daqing 163002, China

Corresponding author: DING Wei, cicy1125@163.com
Received Date: 18 December 2019
Revised Date: 16 February 2020

Fund Project: The project was supported by the National Natural Science Foundation of China 21802061the Doctoral Research Foundation Project of Liaoning Province Department of Science & Technology 20170520440The project was supported by the National Natural Science Foundation of China (21802061), the Doctoral Research Foundation Project of Liaoning Province Department of Science & Technology (20170520440) and the Program for Liaoning Innovative and Entrepreneurship Training in University (201810148029)the Program for Liaoning Innovative and Entrepreneurship Training in University 201810148029

Figures(8)

β-Mo₂C support was first prepared by the temperature-programmed carbonization and the Au/β-Mo₂C catalysts with different Au loadings were then obtained by using the in -situ precipitation method. The Au/β-Mo₂C catalysts were characterized by X-ray diffraction (XRD), scanning transmission electron microscopy (STEM) and nitrogen physisorption; their performance, the thermal stability at the high temperature in particular was then investigated in the reverse water-gas shift (RWGS). The XRD results reveal that the diffraction peaks appeared at 34.44°, 38.02°, 39.44°, 52.12°, 61.53°, 69.62° and 74.65° correspond to the (100), (002), (101), (102), (110), (103) and (200) planes of β-Mo₂C, respectively, whereas no characteristic peak of Au species is detected, suggesting the high dispersion of Au nanoparticles on the Au/β-Mo₂C catalysts with a low Au loading (0.1%-0.5%). The STEM results illustrate that for the Au/β-Mo₂C catalysts with an Au loading of 0.5%-2.0%, gold nanoparticles in the form of atom clusters (about 2 nm) are anchored and uniformly dispersed on the β-Mo₂C surface. The nitrogen physisorption results demonstrate that the Au/β-Mo₂C catalysts have plenty of mesopores. The catalytic evaluation results indicate that the 0.2%Au/β-Mo₂C catalyst exhibits high activity and high selectivity to CO for the RWGS reaction; moreover, after the reaction, the Au nanoparticles are still evenly dispersed and the pore structure remain intact, suggesting that the Au/β-Mo₂C catalyst owns excellent performance and high thermal stability in the he reverse water-gas shift at high temperature.
- in-situ precipitation,
- lattice orientation,
- RWGS reaction,
- thermal stability,
- catalyst
1. [1]
  LI F J, DONG S C, LI S T, LI Z H, LI Y. Measurement and scenario simulation of effect of urbanization on region CO₂ emission based on UES-SD model:A case study in Liaoning Province, China[J]. Chin Geogr Sci, 2015,25(3):350-360. doi: 10.1007/s11769-014-0729-7
2. [2]
  WANG X X, JIANG D B, LANG X M. Climatechange of 4℃ global warming above pre-industrial levels[J]. Adv Atmos Sci, 2018,35(7):757-770. doi: 10.1007/s00376-018-7160-4
3. [3]
  KEDIA S. Approaches to low carbon development in China and India[J]. Adv Clim Change Res, 2016,7:213-221. doi: 10.1016/j.accre.2016.11.001
4. [4]
  SU X, YANG X L, ZHAO B, HUANG Y Q. Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts:Recent advances and the future directions[J]. J Energy Chem, 2017,26:854-867. doi: 10.1016/j.jechem.2017.07.006
5. [5]
  POROSOFF M D, YANG X F, BOSCOBOINIK J A, CHEN J G G. Molybdenum carbide as alternative catalysts to precious metals for highly selective reduction of CO₂ to CO[J]. Angew, 2014,53(26):6705-6709. doi: 10.1002/anie.201404109
6. [6]
  SAGAWA T. Conversion of CO₂ to useful substances with composite iron, nickel, and copper catalysts[J]. J Zhejiang Univ-Sci A, 2018,19(1):80-85. doi: 10.1631/jzus.A1700056
7. [7]
  ÁLVAREZ GALVÁN C, SCHUMANN J, BEHRENS , M , FIERRO J L G, SCHLÖGL R, FREI E. Reverse water-gas shift reaction at the Cu/ZnO interface:Influence of the Cu/Zn ratio on structure-activity correlations[J]. Appl Catal B:Environ, 2016,195:104-111. doi: 10.1016/j.apcatb.2016.05.007
8. [8]
  DUKE A S, XIE K, BRANDT A J, MADDUMAPATABANDI T D, AMMAL S C, HEYDEN A, MONNIER J R, CHEN D A. Understanding active sites in the water-gas shift reaction for Pt-Re catalysts on titania[J]. ACS Catal, 2017,7(4):2597-2606. doi: 10.1021/acscatal.7b00086
9. [9]
  KATTEL S, YAN B H, CHEN J G G, LIU P. CO₂ hydrogenation on Pt, Pt/SiO₂ and Pt/TiO₂:Importance of synergy between Pt and oxide support[J]. J Catal, 2016,343:115-126. doi: 10.1016/j.jcat.2015.12.019
10. [10]
  CHEN X D, SU X, LIANG B L, YANG X L, REN X Y, DUAN H M, HUANG Y Q, ZHANG T. Identification of relevant active sites and a mechanism study for reverse water gas shift reaction over Pt/CeO₂ catalysts[J]. J Energy Chem, 2016,25:1051-1057. doi: 10.1016/j.jechem.2016.11.011
11. [11]
  ZHU X B, QU X, LI X S, LIU J L, LIU J H, ZHU B, SHI C. Selective reduction of carbon dioxide to carbon monoxide over Au/CeO₂ catalyst and identification of reaction intermediate[J]. Chin J Catal, 2016,12(37):2053-2058.
12. [12]
  HE S N, SHAO Z J, SHU Y J, SHI Z P, CAO X M, GAO Q S, HU P J, TANG Y. Enhancing metal-support interactions by molybdenum carbide:an efficient strategy toward the chemoselective hydrogenation of α, β-unsaturated Aldehydes[J]. Chem-Eur J, 2016,16(22):5698-5704.
13. [13]
  ZHAO Li-hong, YAN Jie, FANG Ke-gong, WEI Ling-chao, JIANG Yuan-li, SUN Yu-han. Influence of K content on performance of nano-structured K/Fe/β-Mo₂C catalysts in CO hydrogenation[J]. Nat Gas Ind, 2014,39(3):25-29. doi: 10.3969/j.issn.1001-9219.2014.03.006
14. [14]
  POROSOFF M D, BALDWIN J W, PENG X, MPOURMPAKIS G, WILLAUER H D. Potassium promoted molybdenum carbide as a highly active and selective catalyst for CO₂ conversion to CO[J]. ChemSusChem, 2017,10(11):2408-2415. doi: 10.1002/cssc.201700412
15. [15]
  GENG Wen-hao, LIU Fei, HAN Han, XIAO Lin-fen, WU Wei. Synthesis of N, P-doped C@Mo₂C catalyst and its application in CO₂ hydrogenation[J]. J Fuel Chem Technol, 2017,45(4):458-467. doi: 10.3969/j.issn.0253-2409.2017.04.010
16. [16]
  HU Rui-jue, ZHAO Na-na, LI Jia-jia, ZHANG Man-di, LI Jian-li, SU Hai-quan, GU Xiao-jun. β-Mo₂C catalysts supported on Ni modified mesoporous carbon prepared by different methods and their application in CO hydrogenation to synthesize mixed alcohol[J]. Acta Pet Sin (Pet Process Sect), 2018,34(4):201-210.
17. [17]
  ZHAO Li-hong, YAN Jie, WEI Ling-chao, JIANG Yuan-li, FANG Ke-gong, SUN Yu-han. Preparation of K doped Ni/β-Mo₂C and its performance for CO hydrogenation[J]. Nat Gas Ind, 2015,40(4):23-27.
18. [18]
  PERRET N, WANG X D, DELANNOY L, POTVIN C, LOUIS C, KEANE M A. Enhanced selective nitroarene hydrogenation over Au supported on β-Mo₂C and β-Mo₂C/Al₂O₃[J]. J Catal, 2012,286:172-183. doi: 10.1016/j.jcat.2011.10.026
19. [19]
  CHENG C, ZHANG X L, FU Z M, YANG Z X. Strong metal-support interactions impart activity in the oxygen reduction reaction:Au monolayer on Mo₂C (MXene)[J]. J Phys-Condens Mater, 2018,30(47):112403-112429.
20. [20]
  ROOHI P, ALIZADEH R, FATEHIFAR E. Thermodynamic study and methanothermal temperature-programmed reaction synthesis of molybdenum carbide[J]. Int J Miner Metall Mater, 2016,23(3):339-347. doi: 10.1007/s12613-016-1243-y
21. [21]
  KOIZUMI R, OZDEN S, SAMANTA A, ALVES A P P, MISHRA A, YE G, SILVA G G, VAJTAI R, SINGH A K, TIWARY C S, AJAYAN P M. Origami-inspired 3D interconnected molybdenum carbide nanoflakes[J]. Adv Mater Interfaces, 2018,5(6):1701113-1701120. doi: 10.1002/admi.201701113
22. [22]
  BADDOUR F G, ROBERTS E J, TO A T, WANG L, HABAS S E, RUDDY D A, BEDFORD N M, WRIGHT J, NASH C P, SCHAIDLE J A, BRUTCHEY R L, MALMSTADT N. An exceptionally mild and scalable solution-phase synthesis of molybdenum carbide nanoparticles for thermocatalytic CO₂ hydrogenation[J]. J Am Chem Soc, 2020,142(2):1010-1019. doi: 10.1021/jacs.9b11238
23. [23]
  DHAS N A, GEDANKEN A. Sonochemical synthesis of molybdenum oxide- and molybdenum carbide-silica nanocomposites[J]. Chem Mater, 1997,9(12):3144-3154. doi: 10.1021/cm9704488
24. [24]
  LL X Y, MA D, CHEN LM, AO X H. Fabrication of molybdenum carbide catalysts over multi-walled carbon nanotubes by carbothermal hydrogen reduction[J]. Catal Lett, 2007,116:63-69. doi: 10.1007/s10562-007-9093-x
25. [25]
  WANG T, WANG J, CHEN W, ZHENG X, WANG E. A reusable N-doped-carbon-coated Mo₂C composite counter electrode for high-efficiency dye-sensitized solar cells[J]. Chem-Eur J, 2017,23(68):17311-17317. doi: 10.1002/chem.201703519
26. [26]
  MA D. Strong metal-support interaction (SMSI) effect between metal catalysts and carbide supports[J]. Acta Phys-Chim Sin, 2019,35(8):794-795.
27. [27]
  DUAN X P, TIAN X L, KE J H, YIN YN, ZHENG J W, CHEN J, CAO Zh M, XIE Z X, YUAN YO Z. Size controllable redispersion of sintered Au nanoparticles by using iodohydrocarbon and its implications[J]. Chem Sci, 2016,5:3181-3187.
28. [28]
  CHEN X D, SU X, DUAN H M, LIANG B L, HUANG Y Q, ZHANG T. Catalytic performance of the Pt/TiO₂ catalysts in reverse water gas shift reaction:Controlled product selectivity and a mechanism study[J]. Catal Today, 2017,281:312-318. doi: 10.1016/j.cattod.2016.03.020
1. [1]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
2. [2]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
3. [3]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
4. [4]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
7. [7]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
8. [8]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
9. [9]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
10. [10]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
11. [11]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
12. [12]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
13. [13]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
14. [14]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
15. [15]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
16. [16]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
17. [17]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
18. [18]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
19. [19]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
20. [20]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1282)
HTML views(227)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Au/β-Mo2C catalyst with high thermal stability and its performance in the reverse water-gas shift

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Au/β-Mo₂C catalyst with high thermal stability and its performance in the reverse water-gas shift