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Citation: Yao Jinshui, Wu Yumin, Li Hong, He Binglin. Synthesis and Application of Chiral 2-(2-Pyridyl)4-carbomethoxy-1,3-thiazolidine[J]. Chinese Journal of Applied Chemistry, ;1998, 15(4): 89-91. shu

Synthesis and Application of Chiral 2-(2-Pyridyl)4-carbomethoxy-1,3-thiazolidine

Yao Jinshui ¹ ,
Wu Yumin ¹ ,
Li Hong ² ,
He Binglin ²

1.
Department of Chemical Engineering, Shandong Institute of Light Industry, Ji'nan 250100;
2.
The State Key Labotory of Functional Polymeric Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin

Received Date: 27 October 1997
Revised Date: 15 April 1998

The title ligand(A) was synthesized through condensation of 2-pyridine aldehyde and L-methyl cysteine hydrochloride. The isomers of (A) were separated by column chromatography. The in-situ prepared catalyst from (A) with [Rh(COD)CI]₂ (COD:cyclooctadiene) has been used to catalyze the asymmetric hydrosilylation of acetophenone. The results showed that only the configuration of C₄, but not that of C₂ affected the optical yield and configuration of the products.
- pyridyl-carbomethoxy-thiazolidine,
- ligand,
- asymmetric hydrosilylation
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