Advanced Search

Citation: CHENG Fu-long, GUO He-qin, CUI Jing-lei, HOU Bo, LI De-bao. Guerbet reaction of methanol and ethanol catalyzed by CuMgAlOx mixed oxides: Effect of M2+/Al3+ ratio[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(12): 1472-1481. shu

Guerbet reaction of methanol and ethanol catalyzed by CuMgAlOx mixed oxides: Effect of M2+/Al3+ ratio

  • 1.

    Chongqing Three Gorges University, Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservior, Chongqing 404100, China

  • 2.

    State Key Laborator of Coal Convercion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

  • 3.

    Institute of Resources and Environment Engineering, Shanxi University, Taiyuan 030006, China

  • Corresponding author: GUO He-qin, heqinguo@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
  • Received Date: 4 May 2018
    Revised Date: 14 August 2018

    Fund Project: The project was supported by the National Natural Science Foundation of China (21736007, 21303241)the National Natural Science Foundation of China 21736007the National Natural Science Foundation of China 21303241

Figures(11)

  • A series of hydrotalcite-like derived MgAlOx (MA) and CuMgAlOx (CMA) catalysts with various M2+/Al3+ molar ratios were prepared and evaluated by the aldol condensation reaction of formaldehyde and acetaldehyde and Guerbet reaction of methanol and ethanol, respectively. The acidity and the alkalinity as well as the surface copper species of catalysts were characterized by NH3/CO2-TPD, XPS, H2-TPR and H2-TPD techniques. The results show that the catalytic performance of Guerbet reaction of methanol and ethanol is related to the surface Cu0 species and the number of moderate basic sites. Increasing the specific surface area of Cu0 is beneficial to the dehydrogenation of methanol and ethanol to formaldehyde and acetaldehyde. The increase of the amount of moderate basic sites can promote the condensation reaction of formaldehyde and acetaldehyde.
  • 加载中
    1. [1]

      BIERMAN M, GRUSS H, HUMMEL W, GROEGER H. Guerbet alcohols:From processes under harsh conditions to synthesis at room temperature under ambient pressure[J]. ChemCatChem, 2016,8(5):895-899. doi: 10.1002/cctc.201501241

    2. [2]

      LIU Q, XU G Q, WANG X C, MU X D. Selective upgrading of ethanol with methanol in water for the production of improved biofuel-isobutanol[J]. Green Chem, 2016,18(9):2811-2818. doi: 10.1039/C5GC02963E

    3. [3]

      AJJOU A N, ALPER H. A new, efficient, and in some cases highly regioselective water-soluble polymer rhodium catalyst for olefin hydroformylation[J]. J Am Chem Soc, 1998,120(7):1466-1468. doi: 10.1021/ja973048u

    4. [4]

      GUPTA M, SMITH M L, SPIVEY J J. Heterogeneous catalytic conversion of dry syngas to ethanol and higher alcohols on Cu-cased catalysts[J]. ACS Catal, 2011,1(6):641-656. doi: 10.1021/cs2001048

    5. [5]

      ANDRIANARY P, JENNER G, LIBS S, TELLER G. Homogeneous catalysis of CO2-H2 reactions-homologation of C-3 alcohols[J]. J Mol Catal, 1987,39(1):93-103.

    6. [6]

      GUERBET M. Condensation of isopropylic alcohol with its sodium derivative; formation of methylisobutylcarbinol and dimethyl-2, 4-heptanol-6[J]. Cr Hebd Acad Sci, 1909,149:129-132.

    7. [7]

      WINGAD R L, BERSTROEM E J E, EVERETT M, PELLOW K J, WASS D F. Catalytic conversion of methanol/ethanol to isobutanol-a highly selective route to an advanced biofuel[J]. Chem Commun, 2016,52(29):5202-5204. doi: 10.1039/C6CC01599A

    8. [8]

      DI COSIMO J I, APESTEGUI A C R, GINES M J L, IGLESIA E. Structural requirements and reaction pathways in condensation reactions of alcohols on MgyAlOx catalysts[J]. J Catal, 2000,190(2):261-275. doi: 10.1006/jcat.1999.2734

    9. [9]

      QIU Kun-zan, GUO Wen-wen, WANG Hai-xia, ZHU Ling-jun, WANG Shu-rong. Influence of catalyst structure on performance of Cu/SiO2 in hydrogenation of methyl acetate[J]. Acta Phys-Chim Sin, 2015,31(6):1129-1136.  

    10. [10]

      FU Peng, LI Yong-gang, NING Chun-li. Hydrogenation of sec-butyl acetate to sec-butyl alcohol and ethanol over Cu/ZnO/Al2O3 catalyst[J]. Ind Catal, 2017,25(4):68-73. doi: 10.3969/j.issn.1008-1143.2017.04.012

    11. [11]

      LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. J Fuel Chem Technol, 2015,43(6):677-683. doi: 10.3969/j.issn.0253-2409.2015.06.006 

    12. [12]

      GAO P, LI F, ZHAO N, XIAO F K, WEI W, ZHONG L S, SUN Y H. Influence of modifier (Mn, La, Ce, Zr and Y) on the performance of Cu/Zn/Al catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol[J]. Appl Catal A:Gen, 2013,468:442-452. doi: 10.1016/j.apcata.2013.09.026

    13. [13]

      GAO Peng, LI Feng, ZHAO Ning, WANG Hui, WEI Wei, SUN Yu-han. Preparation of Cu/Zn/Al/(Zr)/(Y) catalysts from hydrotalcite-like precursors and their catalytic performance for the hydrogenation of CO2 to methanol[J]. Acta Phys-Chim Sin, 2014,30(6):1155-1162.  

    14. [14]

      STOSIC D, HOSOGLU F, BENNICI S, TRAVET A, CAPRON M, DUMEIGNIL F, COUTURIER J L, DUBOIS J L, AUROUX A. Methanol and ethanol reactivity in the presence of hydrotalcites with Mg/Al ratios varying from 2 to 7[J]. Catal Commun, 2017,8:14-18.  

    15. [15]

      SHEN J Y, TU M, HU C. Structural and surface acid/base properties of hydrotalcite-derived MgAlO oxides calcined at varying temperatures[J]. J Solid State Chem, 1998,137(2):295-301. doi: 10.1006/jssc.1997.7739

    16. [16]

      XI Jing-yu, WANG Zhi-fei, WANG Wei-ping, LÜ Gong-xuan. In-situ XPS for reaction mechanism of methanol decomposition over Cu-Ni/Zn catalyst[J]. Acta Phys-Chim Sin, 2002,18(1):82-86. doi: 10.3866/PKU.WHXB20020119

    17. [17]

      HUANG Z W, CUI F, XUE J J, ZUO J L, CHEN J, XIA C G. Cu/SiO2 catalysts prepared by hom-and heterogeneous deposition-precipitation methods:Texture, structure, and catalytic performance in the hydrogenolysis of glycerol to 1, 2-propanediol[J]. Catal Today, 2012,183(1):42-51.  

    18. [18]

      KANNAN S, DUBEV A, KNOZINGER H. Synthesis and characterization of CuMgAl ternary hydrotalcites as catalysts for the hydroxylation of phenol[J]. J Catal, 2005,231(2):381-392.  

    19. [19]

      GAO P, LI F, ZHAN H J, ZHAO N, XIAO F K, WEI W, ZHONG L S, WANG H, SUN Y H. Influence of Zr on the performance of Cu/Zn/Al/Zr catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol[J]. J Catal, 2013,298:51-60. doi: 10.1016/j.jcat.2012.10.030

  • 加载中
    1. [1]

      Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al3+ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005

    2. [2]

      Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO2 Methanation of Derived Ni-Al2O3 Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

    3. [3]

      Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026

    4. [4]

      Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO2 Hydrogenation by Decoration of K on MoS2 Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017

    5. [5]

      Tianlong Zhang ,  Rongling Zhang ,  Hongsheng Tang ,  Yan Li ,  Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006

    6. [6]

      Wenjuan Tan , Yong Ye , Xiujuan Sun , Bei Liu , Jiajia Zhou , Hailong Liao , Xiulin Wu , Rui Ding , Enhui Liu , Ping Gao . Building P-Poor Ni2P and P-Rich CoP3 Heterojunction Structure with Cation Vacancy for Enhanced Electrocatalytic Hydrazine and Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(6): 2306054-0. doi: 10.3866/PKU.WHXB202306054

    7. [7]

      Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti3C2Tx MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015

    8. [8]

      Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuOx/TiO2 Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 2408015-0. doi: 10.3866/PKU.WHXB202408015

    9. [9]

      Lijun Yue ,  Siya Liu ,  Peng Liu . 不同晶相纳米MnO2的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005

    10. [10]

      Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS2 Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024

    11. [11]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    12. [12]

      Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

    13. [13]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    14. [14]

      Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

    15. [15]

      Xueli Mu ,  Lingli Han ,  Tao Liu . Quantum Chemical Calculation Study on the E2 Elimination Reaction of Halohydrocarbon: Designing a Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 68-75. doi: 10.12461/PKU.DXHX202404057

    16. [16]

      Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co2MnO4 in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021

    17. [17]

      Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO2 Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028

    18. [18]

      Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt3M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188

    19. [19]

      Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224

    20. [20]

      Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100

Get Citation
PDF
XML
Metrics
  • PDF Downloads(10)
  • Abstract views(1320)
  • HTML views(234)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return