Citation: YANG Long, KONG Ling, SHI Hui-xian, QIN Shu-hao, ZHANG Wei, GU Min-yan, SHEN Zheng, ZHANG Ya-lei. Study on the synthesis of propylene glycol through cellulose hydrogenation using alkaline promoted Ni-W/β-zeolite catalysts[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(1): 48-54. shu

Study on the synthesis of propylene glycol through cellulose hydrogenation using alkaline promoted Ni-W/β-zeolite catalysts

YANG Long ^1,2 ,
KONG Ling ^1,2 ,
SHI Hui-xian ¹ ,
QIN Shu-hao ³ ,
ZHANG Wei ^1,2 ,
GU Min-yan ² ,
SHEN Zheng ^1,2,*,, ,
ZHANG Ya-lei ^1,2

1.
National Engineering Research Center of Protected Agriculture, Tongji University, Shanghai 200092, China
2.
State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China
3.
The National Engineering Research Center for Compounding and Modification of Polymer Materials, Guiyang 550014, China

Corresponding author: SHEN Zheng, shenzheng@tongji.edu.cn
Received Date: 27 July 2016
Revised Date: 21 October 2016

Fund Project: the National Natural Science Foundation of China 51625804the Fundamental Research Funds for the Central Universities 2870219026the National Natural Science Foundation of China 21376180the Fundamental Research Funds for the Central Universities 2870219028the International Collaborative Project from Shanghai Science and Technology Commission 14230710800the National Natural Science Foundation of China 21676205

Figures(6)

A series of Ni-W/β zeolite catalysts were prepared via incipient impregnation method in order to improve the yield of 1, 2-propylene glycol (1, 2-PG) in the alcohol products of cellulose hydrogenation. Under the reaction conditions of 240℃ and 6.0 MPa H₂ for 30 min, the complete conversion of cellulose was obtained and the yields of 1, 2 propylene glycol and ethylene glycol (EG) were 19.3% and 45.3%, respectively. Different from other supports, the selectivity of 1, 2-PG was highly improved when β zeolite was used. The selectivity of 1, 2-PG was further improved after the addition of alkaline, and the yield of 1, 2-PG was up to 32.5% especially for Ba (OH)₂. The function of alkaline catalysts in the reaction was also discussed based on a series of reactions using glucose as the substrate, indicating that alkaline was favorable for the isomerization of glucose to fructose and thus promoted the conversion of cellulose into 1, 2-PG. After two cycles of reuse, the yield of 1, 2-PG and EG slightly decreased (3.9% and 4.1%, respectively).
- Ni-W/β zeolite,
- cellulose,
- 1, 2-propylene glycol,
- alkaline catalysts,
- hydrogenation
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