Citation: LIU Heng, KAN Qiu-bin. Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(11): 1380-1387. shu

Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization

LIU Heng ^1,*,, ,
KAN Qiu-bin ²

1.
Research Center for Nanotechnology, Changchun University of Science and Technology, Changchun 130022, China
2.
College of Chemistry, Jilin University, Changchun 130023, China

Corresponding author: LIU Heng, liuhengjlu@163.com
Received Date: 24 June 2016
Revised Date: 8 August 2016

Fund Project: Youth Fund of Changchun University of Science and Technology XJJLG-2015-12

Figures(8)

A novel hierarchical porous IM-5 (IM-5-K) was synthesized by using mesoporous silica KIT-6 as the silica sources. The physical properties and acidities of the samples were characterized by XRD, SEM, TEM, BET and NH₃-TPD. Moreover, Mo-modified catalyst, Mo-IM-5-K was prepared for non-oxidative aromatization of methane. Compared with Mo-IM-5-C, the Mo-IM-5-K catalyst showed higher conversion of methane and yields of aromatics. In addition, Mo-IM-5-K exhibited better stability than Mo-IM-5-C. Different activities and stabilities of the catalysts may be due to their different structure properties and acidities. The existence of secondary mesoporous systems may influence the location and state of the active Mo species, simultaneously lead to easier access to the active sites for reactants and better diffusion of aromatic products, thus improvs the activities of the catalysts.
- IM-5,
- mesoporous,
- molybdenum,
- methane dehydroaromatiztion
1. [1]
  MA S, GUO X, ZHAO L, SCOTTC S, BAO X. Recent progress in methane dehydroaromatization:From laboratory curiosities to promising technology[J]. J Energy Chem, 2013,22(1):1-20. doi: 10.1016/S2095-4956(13)60001-7
2. [2]
  LUNSFORD J H. Catalytic conversion of methane to more useful chemicals and fuels:A challenge for the 21st century[J]. Catal Today, 2000,63(2/4):165-174.
3. [3]
  XU C, GUAN J, WU S, JIA M, WU T, KAN Q. Catalytic performance of zeolite ITQ-13 with 9-and 10-member rings for methane dehydroaromation[J]. React Kinet Mech Catal, 2010,99(1):193-199.
4. [4]
  LIU H, HU J, LI Z, WU S, LIU L, GUAN J, KAN Q. Synthesis of zeolite IM-5 under rotating and static conditions and the catalytic performance of Mo/H-IM-5 catalyst in methane non-oxidative aromatization[J]. Kinet Catal, 2013,54(4):443-450. doi: 10.1134/S0023158413040083
5. [5]
  XU Yue-bing, LU Jiang-yin, WANG Ji-de, ZHANG Zhan-guo. Mo-based zeolite catalysts and oxygen-free methane aromatization[J]. Prog Chem, 2011,23(1):90-106.
6. [6]
  WANG D, KAN Q, XU N, WU P, WU T. Study on methane aromatization over MoO₃/HMCM-49 catalyst[J]. Catal Today, 2004,93:75-80.
7. [7]
  LIU H, YANG S, WU S, SHANG F, YU X, XU C, GUAN J, KAN Q. Synthesis of Mo/TNU-9(TNU-9 Taejon National University No. 9) catalyst and its catalytic performance in methane non-oxidative aromatization[J]. Energy, 2011,36:1582-1589. doi: 10.1016/j.energy.2010.12.073
8. [8]
  LIU H, YANG S, HU J, SHANG F, LI Z, XU C, GUAN J, KAN Q. A comparison study of mesoporous Mo/H-ZSM-5 and conventional Mo/H-ZSM-5 catalysts in methane non-oxidative aromatization[J]. Fuel Process Technol, 2012,96:195-202. doi: 10.1016/j.fuproc.2011.12.034
9. [9]
  WU P, KAN Q, WANG X, WANG D, XING H, YANG P, WU T. Acidity and catalytic properties for methane conversion of Mo/HZSM-5 catalyst modified by reacting with organometallic complex[J]. Appl Catal A:Gen, 2005,282(1/2):39-44.
10. [10]
  YANG Jian-hua, YU Su-xia, HU Hui-ye, CHU Nai-bo, LU Jin-ming, YIN De-hong, WANG Jin-qu. Synthesis of hierarchical HZSM-5 microspheres without second template and their application in methane dehydroaromatization[J]. Chin J Catal, 2011,32(2):362-367.
11. [11]
  WANG Di-yong, WANG Jin-qu, YANG Jian-hua, LU Jin-ming, YIN De-hong, ZHANG Yan. Synthesis of ZSM-5 zeolite by vapor-phase method and performance of its Mo-based catalyst for methane dehydroaromatization[J]. Chin J Catal, 2012,33(8):1383-1388.
12. [12]
  ZHANG Hang-fei, MA Ji-yuan, YIN Jin-lian, ZHOU Rong, LU Jiang-yin. Effect of methane dehydroaromatization over modified 6%Mo-0.7%Co/HZSM-5 catalysts in absence of oxidants[J]. Mod Chem Ind, 2015,35(11):77-80.
13. [13]
  GUO X, FANG G, LI G, MA H, FAN H, YU L, MA C, WU X, DENG D, WEI M, TAN D, SI R, ZHANG S, LI J, SUN L, TANG Z, PAN X, BAO X. Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen[J]. Science, 2014,344(6184):616-619. doi: 10.1126/science.1253150
14. [14]
  KLEITZ F, CHOI S H, RYOO R. Cubic Ia3d large mesoporous silica:Synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes[J]. Chem Commun, 2003,9(17):2136-2137.
15. [15]
  OVEISI H, ANAND C, MANO A, AL-DEYAB S S, KALITA P, BEITOLLAHI A, VINU A. Inclusion of size controlled gallium oxide nanoparticles into highly ordered 3D mesoporous silica with tunable pore diameters and their unusual catalytic performance[J]. J Mater Chem, 2010,20(45):10120-10129. doi: 10.1039/c0jm02006k
16. [16]
  CORMA A, MENGUAL J, MIGUEL P J. IM-5 zeolite for steam catalytic cracking of naphtha to produce propene and ethene. An alternative to ZSM-5 zeolite[J]. Appl Catal A:Gen, 2013,460-461(11):106-115.
17. [17]
  LIU H, WU S, GUO Y, SHANG F, YU X, MA Y, XU C, GUAN J, KAN Q. Synthesis of Mo/IM-5 catalyst and its catalytic behavior in methane non-oxidative aromatization[J]. Fuel, 2011,90:1515-1521. doi: 10.1016/j.fuel.2010.11.027
18. [18]
  VENNESTRØM P N R, JANSSENS T V W, KUSTOV A, GRILL M, PUIG-MOLINA A, LUNDEGAARD L F, TIRUVALAM R R, CONCEPCIÓN P, CORMA A. Influence of lattice stability on hydrothermal deactivation of Cu-ZSM-5 and Cu-IM-5 zeolites for selective catalytic reduction of NO_x by NH₃[J]. J Catal, 2014,309(6):477-490.
19. [19]
  CHEN Jun-wen, ZHANG Chao, WANG Yong-rui, SUN Min, MU Xu-hong, SHU Xing-tian. Catalytic performance of modified IM-5 zeolite in alkylation of toluene with methanol[J]. Acta Pet Sin (Pet Process Sect), 2013,29(5):757-766.
20. [20]
  PARLETT C M, WILSON K, LEE A F. Hierarchical porous materials:Catalytic applications[J]. Chem Soc Rev, 2013,42(9):3876-3893. doi: 10.1039/C2CS35378D
21. [21]
  SACHSE A, WUTTKE C, DÍAZ U, DESOUZA M O. Mesoporous Y zeolite through ionic liquid based surfactant templating[J]. Microporous Mesoporous Mater, 2015,217:81-86. doi: 10.1016/j.micromeso.2015.05.049
22. [22]
  KOOHSARYAN E, ANBIA M. Nanosized and hierarchical zeolites:A short review[J]. Chin J Catal, 2016,37(4):447-467. doi: 10.1016/S1872-2067(15)61038-5
23. [23]
  CUI Sheng-hang, ZHANG Jun-tao, SHEN Zhi-bing. Hierarchical ZSM-5 zeolite:Synthesis and catalytic applications[J]. Chem Ind Eng Prog, 2015,34(9):3311-3316.
24. [24]
  LIU Xiao-ling, JIANG Jian-zhun, ZHANG Ming-sen. Research advance in synthesis of hierarchical molecular sieves[J]. Ind Catal, 2016,24(3):10-18.
25. [25]
  LI B, LI S, LI N, CHEN H, ZHANG W, BAO X, LIN B. Structure and acidity of Mo/ZSM-5 synthesized by solid state reaction for methane dehydrogenation and aromatization[J]. Microporous Mesoporous Mater, 2006,88(1/3):244-253.
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