Citation: LIN Chun-Xiang, TIAN Chen, LIU Yi-Fan, CHENG Yang-Jian, LIN Zhang, LIU Ming-Hua. Preparation and Characterization of a Novel Spherical Cellulose Adsorbent for Reduction Adsorption of Trichloroacetic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1401-1408. shu

Preparation and Characterization of a Novel Spherical Cellulose Adsorbent for Reduction Adsorption of Trichloroacetic Acid

LIN Chun-Xiang ^a,b ,
TIAN Chen ^a,b ,
LIU Yi-Fan ^a,b ,
CHENG Yang-Jian ^a,b ,
LIN Zhang ^a,b ,
LIU Ming-Hua ^a,b,,

1.
a College of Environment & Resources, Fuzhou University, Fuzhou 350108, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LIU Ming-Hua,
Received Date: 21 October 2013
Available Online: 22 July 2014
Fund Project: Science & Technology Development Fund of Fuzhou University (2012-XY-10, 2014-XQ-11) (JK2013004, JA12040)the National Natural Science Foundation of China (41372346) (2012-XY-10, 2014-XQ-11)

A novel spherical cellulose adsorbent has been prepared by homogeneous graft polymerization of N,N'-methylenebisacrylamide (MBA) onto cellulose in an ionic liquid, 1-N-butyl-3-methylimidazolium chloride (BMIMCl), which was then partially amine methylated through Mannich reaction to get bifunctionalized materials containing both amide and sulphinate moities. Factors affecting the attachment of functional groups were investigated. The adsorbent was characterized by Elemental Analysis (EA), Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscope (SEM). Cellulose adsorbent was then tested for its potential applications in the reduction adsorption of trichloroacetic acid (TCAA) from aqueous solutions.
- cellulose adsorbent,
- reduction adsorption,
- trichloroacetic acid,
- Mannich reaction
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