Citation: XUE Li-Ping, LIU Yue-Cheng, HAN Yun-Hu, TIAN Chong-Bin, LI Qi-Peng, LIN Ping, DU Shao-Wu. New Zn(Ⅱ)/M(I) (M=Na, K and Rb) Metal-organic Frameworks Based on 5-Methylisophthalic Acid Ligand: Syntheses, Structures and Fluorescent Property[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1191-1198. shu

New Zn(Ⅱ)/M(I) (M=Na, K and Rb) Metal-organic Frameworks Based on 5-Methylisophthalic Acid Ligand: Syntheses, Structures and Fluorescent Property

XUE Li-Ping ^a,b ,
LIU Yue-Cheng ^a ,
HAN Yun-Hu ^a,b ,
TIAN Chong-Bin ^a ,
LI Qi-Peng ^a,b ,
LIN Ping ^a,, ,
DU Shao-Wu ^a

a.
a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LIN Ping,
Received Date: 22 January 2014
Available Online: 7 May 2014
Fund Project: This work was supported by the National Basic Research Program of China (973 Program, 2012CB821702) (973 Program, 2012CB821702)

Reactions of Zn(NO₃)₂·6H₂O and MNO₃ (M=Na, K and Rb) with H₂mip (H₂mip=5-methylisophthalic acid) in DMF (DMF=N,N'-dimethylformamide) resulted in the formation of novel heterometallic metal-organic frameworks (Me₂NH₂)[ZnM(mip)₂] (1: M=Na; 2: M=K; 3: M=Rb, mip=5-methylisophthalate dianion for 1~3). These complexes belong to the monoclinic system, space group P2/c and have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveal that 1~3 are 3D isomorphic structures based on a trinuclear unit {ZnM₂(μ₂-COO)₂(μ₃-COO)₂} and exhibit pcu topological net and blue fluorescence.
- heterometallic,
- solvothermal synthesis,
- photoluminescence
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