Citation: LIU Yong-Lua, CHEN Yan-Mei, GAO Qian, LIU Wei, LI Ya-Hong, LI Wu. Zn^Ⅱ, Ni^Ⅱ, and Mn^Ⅱ Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1171-1183. shu

Zn^Ⅱ, Ni^Ⅱ, and Mn^Ⅱ Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties

LIU Yong-Lua ^a ,
CHEN Yan-Mei ^a,b ,
GAO Qian ^a ,
LIU Wei ^a ,
LI Ya-Hong ^a,c,, ,
LI Wu ^b

a.
a. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China;
b.
b. Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China;
c.
c. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Corresponding author: LI Ya-Hong,
Received Date: 16 January 2014
Available Online: 3 April 2014
Fund Project:

The employment of N-hydroxy-pyridine-2-carboxamidine in the coordination chemistry of zinc(Ⅱ), nickel(Ⅱ) and manganese(Ⅱ) under solvothermal conditions is reported. Four complexes of compositions, [Zn₂(O₂CMe)₃{(py)C(NH₂)NOH}₄](OH) (1), [Zn₄(OH)₂{(py)C(NH₂)-NO}₄Cl₂]·MeCN (2), [Ni(SO₄)(H₂O){(py)C(NH2)NOH}₂]·H₂O (3) and [Mn(SO₄){(py)C(NH₂)-NOH}₂]_n (4), have been synthesized by rationally choosing different metal salts and dexterously employing acetate and sulfate ions as the bridging groups. Luminescent properties for 2 suggested strong emission in the solid state at room temperature. Variable temperature (2.0~300 K) magnetic studies for the linear chain complex 4 indicate weak antiferromagnetic Mn(Ⅱ)…Mn(Ⅱ) exchange interactions.
- solvothermal,
- N-hydroxy-pyridine-2-carboxamidine,
- luminescence,
- magnetic property
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