Citation: ZHANG Zhao-Ming, LI Guo-Ling, ZHAO Yun, NI Zhong-Hai. Two New Organic Supramolecular Complexes Based on 2,3,6,7-Tetrahydroxyl-9, 10-dimethyl-9,10-dihydro-9,10-ethanoanthracene and 4,4'-Bipyridine or 4,4'-Bipyridinylethane[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 835-840. shu

Two New Organic Supramolecular Complexes Based on 2,3,6,7-Tetrahydroxyl-9, 10-dimethyl-9,10-dihydro-9,10-ethanoanthracene and 4,4'-Bipyridine or 4,4'-Bipyridinylethane

1.
School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, China

Received Date: 28 November 2013
Available Online: 11 February 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21176246) (No. 21176246)

Two new organic supramolecular cocrystal complexes C₁₈H₁₈O₄·C₁₀H₈N₂ (Ⅰ) and C₁₈H₁₈O₄·C₁₂H₁₀N₂ (Ⅱ) (C₁₈H₁₈O₄=2,3,6,7-tetrahydroxyl-9,10-dimethyl-9,10-dihydro-9,10-ethanoanthracene (LH₄), C₁₀H₈N₂=4,4'-bipyridine (bpy) and C₁₂H₁₀N₂=4,4'-bipyridinylethane (bpe)) have been obtained by mixing LH₄ with corresponding bpy or bpe ligand. The two complexes have been determined by X-ray crystal structure analysis, elemental analysis and IR analysis. Compound Ⅰ crystallizes in the orthorhombic Pnma with a=9.7078(4), b=22.4974(10), c=20.6272(9)Å, V=4505.0(3)Å³, M_r=454.51, D_c=1.340 g·cm^-3, μ=0.09 mm^-1, F(000)=1920, Z=8, R=0.0503 and wR=0.1360. Compound Ⅱ crystallizes in monoclinic C2/c with a=29.944(6), b=9.820(2), c=22.643(5)Å, V=5048.4(18)Å³, M_r=480.54, D_c=1.265 g cm^-3, μ=0.084 mm^-1, F(000)=2032, Z=8, R=0.0548 and wR=0.1600. X-ray single-crystal structure analysis shows that two-dimensional (2D) layer supramolecular structures are formed through hydrogen bonds and π-π interactions in the two complexes. IR analysis also indicates that there are only associated hydroxyl groups in the two complexes.
- 2,3,6,7-tetrahydroxy-9,10-dimethyl-9,10-dihydro-9,10-ethanoanthracene,
- supramolecular structure,
- 4,4'-bipyridine,
- 4,4'-bipyridinylethane,
- hydrogen bond
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