Citation: Song Lin ZHANG, Yong Min ZHANG. Reductive Cleavage of the S-Si Bond in Phenylthio-trimethylsilane:A Novel Method for the Synthesis of Thiolesters[J]. Chinese Chemical Letters, ;1998, 9(1): 25-27. shu

Reductive Cleavage of the S-Si Bond in Phenylthio-trimethylsilane:A Novel Method for the Synthesis of Thiolesters

Department of Chemistry, Hangzhou University. Hangzhou 3100028 China

Received Date: 11 September 1997

Fund Project: We are grateful to the National Natural Science Foundation of China and the Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences for financial support.

Phenylthiotrimethylsilane is reduced by samarium diiodide to yield samarium phenylthiolate. This new thiolate anion species reacts with acyl chlorides mildly to give thiolesters in good yields.
- Phenylthiotrimethylsilane,
- Samarium diiodide,
- Thiolester

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