Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Synthesis, Crystal Structures and Magnetic Properties of Ni(Ⅱ) and Mn(Ⅱ) Coordination Polymers Constructed from 5-(2'-carboxylphenyl) Nicotate and 2,2'-Biimidazole[J]. Chinese Journal of Structural Chemistry, ;2014, 33(3): 434-440. shu

Synthesis, Crystal Structures and Magnetic Properties of Ni(Ⅱ) and Mn(Ⅱ) Coordination Polymers Constructed from 5-(2'-carboxylphenyl) Nicotate and 2,2'-Biimidazole

a.
a. School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;
b.
b. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GAO Zhu-Qing,
Received Date: 5 August 2013
Available Online: 22 October 2013
Fund Project: Funded by the National Natural Science Foundation of Shanxi Province (No. 2013011011-6) (No. 2013011011-6)

Two coordination polymers, namely {[Ni(cpna)(H₂biim)(H₂O)]·H₂O}_n (1) and {[Mn(cpna)(H₂biim)]·H₂O}_n (2) (H₂cpna=5-(2'-carboxylphenyl) nicotic acid, H₂biim=2,2'-biimidazole) have been hydrothermally synthesized and characterized by elemental analysis, IR, TG, magnetic properties, and single-crystal X-ray diffraction. Compound 1 exhibits a one-dimensional (1D) step-like chain structure, which further builds a three-dimensional (3D) supra-molecular architecture via O-H…O and N-H…O hydrogen-bonding and π-π stacking interactions. Compound 2 possesses a one-dimensional (1D) double chain structure, which is further assembled into a 3D supramolecular framework by N-H…O hydrogen bonding and π-π stacking interactions. Magnetic susceptibility measurement indicates that compound 1 shows a weak antiferromagnetic coupling between the nearest Ni(Ⅱ) centers, with g=2.11 and J=-1.87 cm^-1.
- coordination polymer,
- crystal structrue,
- magnetic properties
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