Citation: GONG Xue, WEI Hang, LUO Kai-Jun, LI Quan. UV-Vis Spectrum and the Third-order Nonlinear Optical Properties of the Chiral Camphor-derived β-diketonate Platinum Complexess[J]. Chinese Journal of Structural Chemistry, ;2014, 33(3): 422-428. shu

UV-Vis Spectrum and the Third-order Nonlinear Optical Properties of the Chiral Camphor-derived β-diketonate Platinum Complexess

1.
Key Laboratory of Advanced Functional Materials, Sichuan Province Higher Education System, College of Chemistry and Material Science, Sichuan Normal University, Chengdu 610066, China

Corresponding author: LI Quan,
Received Date: 22 May 2013
Available Online: 13 January 2014
Fund Project: Project supported by the National Natural Science Foundation of China (21172161) (21172161)

UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G^* level. The results showed that the introduction of electron-drawing group -CF₃ and -C₃F₇ on β-diketonate made the strongest absorption peak red-shift and the lowest energy absorption blue-shied. Introduction of -OC₂H₅ on the benzene or pyridine ring made the lowest energy absorption blue-shift. When the -C₂H₃ was introduced on the benzene or pyridine ring, the lowest energy absorption was red-shifted. Introduction of electron-donating group on β-diketonate can enlarge their nonlinear optical properties. On the contrary, the introduction of electron-drawing group dropped it down.
- camphor-derived β-diketonate,
- platinum complexes,
- the third-order nonlinear optical properties,
- UV-Vis absorption spectrum,
- density functional theory
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