Citation: PENG Cheng-Dong, LI Ya-Si, ZHUANG Ting-Ting, YIN Fan-Wen, ZENG Qing-Xin. Hydrothermal Synthesis and Structural Characterization of a Novel 3-D Open Framework Zinc Phosphate Microporous Compound (C₅N₂H₁₄)·[Zn₃(OH₂)(PO₄)₂(HPO₄)][J]. Chinese Journal of Structural Chemistry, ;2014, 33(3): 333-338. shu

Hydrothermal Synthesis and Structural Characterization of a Novel 3-D Open Framework Zinc Phosphate Microporous Compound (C₅N₂H₁₄)·[Zn₃(OH₂)(PO₄)₂(HPO₄)]

1.
College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China

Corresponding author: ZENG Qing-Xin,
Received Date: 24 June 2013
Available Online: 23 December 2013
Fund Project:

One novel organically templated zincophophate (C₅N₂H₁₄)·[Zn₃(OH₂)(PO₄)₂(HPO₄)] has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction together with elemental analysis, infrared spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. The title compound crystallizes in the monoclinic space group P2₁/n, with a=9.7904(11), b=14.0287(14), c=11.8651(13) Å, β=104.690(3)°, V=1576.4(3) Å³, Z=4, T=296(2) K, M_r=601.31 and D_c=2.533 g/cm³. The compound consists of a macroanionic [Zn₃(OH₂)(PO₄)₂(HPO₄)]^2- framework and (C₅N₂H₁₄)²⁺ cations, and its structure is built up from ZnO₃(OH₂), ZnO₄, HPO₄ and PO₄ tetrahedral units that result in 4, 8 and 10-ring channels.
- zinc,
- phosphate,
- hydrothermal synthesis,
- 3D open framework,
- microporous compound
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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