Citation: ZHU Xiao-Fei, WANG Ning, XIE Xiao-Yan, HOU Rui-Bin, ZHOU De-Feng, LI Ya-Feng, HU Jun, LI Xin-Yuan, LIU He, NIE Wang. A New 3D Metal-organic Framework with Tetranuclear Cadmium(Ⅱ) Clusters:Synthesis, Structure, and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2014, 33(2): 277-283. shu

A New 3D Metal-organic Framework with Tetranuclear Cadmium(Ⅱ) Clusters:Synthesis, Structure, and Luminescent Property

ZHU Xiao-Fei ^a ,
WANG Ning ^b,, ,
XIE Xiao-Yan ^a ,
HOU Rui-Bin ^a ,
ZHOU De-Feng ^a ,
LI Ya-Feng ^c ,
HU Jun ^a ,
LI Xin-Yuan ^a ,
LIU He ^a ,
NIE Wang ^a

1.
a School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China;
2.
b School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;
3.
c School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China

Corresponding author: WANG Ning,
Received Date: 28 January 2013
Available Online: 13 November 2013
Fund Project: This project was supported by the NNSFC (No.20871023) (No.20871023) the Jilin Provincial Science Research Foundation of China (No.20101549) (No.20101549)

A unique metal-organic framework[Cd₂(L)_1.5(μ₃-OH)(H₂O)₂]·2H₂O (1, H₂L=2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group P1, C₃₃H₂₇CdO₁₄, M_r=870.33, a=12.2939(17), b=12.5135(9), c=13.2046(10) Å, α=115.3190(10), β=96.9140(10), γ=109.7950(10)°, V=1641.6(3) Å³, Z=2, D_c=1.761 g/cm³, F(000)=862, μ(MoKα)=1.366 mm^-1, R_int=0.0148, R=0.0240 and wR=0.0639 for 5995 observed reflections with I>2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with (4¹²·6³) topology, in which the tetra-nuclear[Cd₄(μ₃-OH)₂] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail.
- hydrothermal,
- tetranuclear cluster,
- 2,5-dibenzoylterephthalic acid,
- luminescence,
- crystal structure
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