Citation: LI Shu-Jing, LI Ke, QU Bo-Tao, ZHENG Wei. Synthesis, Crystal Structure and Properties of a New Zn(Ⅱ) Coordination Polymer Constructed from 2,3-Pyridine Dicarboxylic Acid and 1,1'-(1,4-Butanediyl)bis(imidazole)[J]. Chinese Journal of Structural Chemistry, ;2014, 33(2): 193-198. shu

Synthesis, Crystal Structure and Properties of a New Zn(Ⅱ) Coordination Polymer Constructed from 2,3-Pyridine Dicarboxylic Acid and 1,1'-(1,4-Butanediyl)bis(imidazole)

LI Shu-Jing ^a,, ,
LI Ke ^a ,
QU Bo-Tao ^b ,
ZHENG Wei ^b

1.
a Department of Chemistry, Zhoukou Normal University, Zhoukou 466001, China;
2.
b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: LI Shu-Jing,
Received Date: 11 July 2013
Available Online: 16 September 2013
Fund Project: the Foundation of Henan Educational Committee (13A150102) (122102210250) and the key disciplines of analytical chemistry of Henan province (13A150102)

A new coordination polymer, namely[Zn(pdc)(bbi)]_n {H₂pdc=2,3-pyridine dicar-boxylic acid, bbi=1,1'-(1,4-butanediyl)bis(imidazole)}, has been prepared under hydrothermal conditions and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P2₁/n with a=8.436(3), b=16.988(5), c=12.106(4) Å, β=92.204(5)°, V=1733.6(9) Å³, Z=4, C₁₇H₁₇N₅O₄Zn, M_r=420.73, D_c=1.612 g/cm³, F(000)=864, μ(MoKa)=0.452 mm^-1, the R=0.0672 and wR=0.1645. In the mononuclear complex, each Zn(Ⅱ) is five-coordinated by one carboxylate O and one pyridyl N atoms from one pdc anion, one carboxylate O atom from another pdc anion, and two N atoms from two bib ligands. The Zn(Ⅱ) ions are connected by pdc ligands to form skeleton chains, and bbi ligands further link them to construct a 2D framework. The thermal and luminescence properties of the complex were also investigated.
- 2,3-pyridine dicarboxylic acid,
- 1,1'-(1,4-butanediyl)bis(imidazole),
- zinc complex,
- crystal structure,
- thermal analysis,
- luminescence
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