Citation: Chun Juan LIU, Li Hua LIU, Shi Yan YANG, Wei GAO, Ze Min XIE. A Novel Method to Synthesize Polyorganozircosilazane[J]. Chinese Chemical Letters, ;2002, 13(12): 1225-1226. shu

A Novel Method to Synthesize Polyorganozircosilazane

State Key Laboratory of Engineering Plastics, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080

Received Date: 22 February 2002

Fund Project: We gratefully acknowledge the National Natural Sciences Foundation of China (No.50072033) for the financial support.

A new kind of polyorganozircosilazane as Si/Zr/C/N-based ceramic precursor was synthesized from the condensation reaction of hexamethylcyclotrisilazane lithium salts (D₃^NLi) and zirconium tetrachloride (ZrCl₄). In the presence of N, N, N', N'-tetramethyl ethylene diamine (TMEDA), polyorganozircosilazane was obtained in high yield.
- Polyorganozircosilazane,
- Si/Zr/C/N-based ceramic precursor,
- synthesis
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