Citation: Zhang Ping, Peng Peng, Hou Bingbing, Ma Huiting, Zhai Cuiping. Studies on the Interactions of Glucose and Inositol with Ascorbic Acid[J]. Chemistry, ;2018, 81(3): 258-266. shu

Studies on the Interactions of Glucose and Inositol with Ascorbic Acid

Institute of Fine Chemical and Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004

Corresponding author: Zhai Cuiping, zhaicuiping@henu.edu.cn
Received Date: 19 October 2017
Accepted Date: 12 December 2017

Figures(10)

The interactions of glucose and inositol respectively with ascorbic acid (AA) were studied by electrochemistry, density functional theory methods and atoms in molecules analysis. The electrochemical results of the two mixed systems in aqueous solution and phosphate buffer saline (PBS) solution showed that the hydrogen atoms on the enediol of AA can form hydrogen bonds with the oxygen atoms on hydroxyl of glucose/inositol, making the electro-oxidation reaction of AA more difficult, which is further confirmed by quantum chemical calculation.
- Ascorbic acid,
- Glucose,
- Inositol,
- Interaction,
- Electrochemistry,
- Quantum chemical calculations
1. [1]
  J Du, J J Cullen, G R Buettner. Biochim. Biophys. Acta, 2012, 1826(2):443~457.
2. [2]
  S J Padayatty, A Katz, Y H Wang et al. J. Am. Coll. Nutr., 2003, 22(1):18~35.
3. [3]
  I F Hu, T Kuwana. Anal. Chem., 1986, 58(14):3235~3239.
4. [4]
  J Rozgaité, A Pocius, J Kuly. J. Electroanal. Chem., 1983, 154(1-2):121~128.
5. [5]
  Y M Chen, H Li. J. Phys. Chem. A, 2010, 114(43):11719~11724.
6. [6]
  I B Afanasev, V V Grabovetskii, N S Kuprianova. J. Chem. Soc. Perk. Transac., 1987, (3):281~285.
7. [7]
  Y Dimitrova. Spectrochim. Acta A, 2006, 63(2):427~437.
8. [8]
9. [9]
  P Li, Y Z Zhai, W H Wang et al. Struct. Chem., 2011, 22(4):783~793.
10. [10]
  E A Kazoyan, A M Terzyan, S A Markaryan. Russ. J. Phys. Chem. A, 2011, 85(4):612~616.
11. [11]
  N Niazazari, A L Zatikyan, S A Markarian. Spectrochim. Acta A, 2013, 110:217~225.
12. [12]
  D Martín-Yerga, J Carrasco-Rodríguez, J L G Fierro et al. Electrochim. Acta, 2017, 229:102~111.
13. [13]
  S Sharma, M Goodarzi, J Delanghe et al. Appl. Spectrosc., 2014, 68(4):398~405.
14. [14]
  G M Steil, K Rebrin, J Mastrototaro et al. Diabetes Technol. The., 2003, 5(1):27~31.
15. [15]
  A I Gopalan, N Muthuchamy, S Komathi et al. Biosens. Bioelectron., 2016, 84:53~63.
16. [16]
  C P Zhai, F Sun, P Zhang et al. J. Mol. Liq., 2016, 223:420~426.
17. [17]
  M Rahimi-Nasrabadi, F Mizani, M Hosseini et al. Spectrochim. Acta A, 2017, 186:82~88.
18. [18]
  E Fisher, S V McLennan, H Tada et al. Diabetes, 1991, 40(3):371~376.
19. [19]
  J J Li, H Q An, J Zhu et al. Sens. Actuat. B, 2016, 235:663~669.
20. [20]
  P K Banipal, M Sharma, N Aggarwal et al. J. Chem. Thermodyn., 2016, 102:322~332.
21. [21]
22. [22]
  S P Jengathe, S S Dhondge, L J Paliwal et al. J. Chem. Thermodyn., 2015, 87:78~87.
23. [23]
24. [24]
  M J Frisch, G W Trucks, H B Schlegel et al. Gaussian 09, Revision D.01; Gaussian, Inc.:Wallingford, CT, 2009.
25. [25]
26. [26]
  T Matsui, Y Kitagawa, M Okumura et al. J. Phys. Chem. A, 2015, 119(2):369~376.
27. [27]
28. [28]
29. [29]
30. [30]
  R N Singh, V Baboo, P Rawat et al. Spectrochim. Acta A, 2012, 94:288~301.
31. [31]
  U Koch, P L A Popelier. J. Phys. Chem., 1995, 99(24):9747~9754.
32. [32]
  M Zahedi-Tabrizi, F Ektefa. Monatshefte für Chemie-Chemical Monthly, 2015, 146(11):1837~1843.
33. [33]
  I Rozas, I Alkorta, J Elguero. J. Am. Chem. Soc., 2000, 122:11154~11161.
1. [1]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
2. [2]
  Xueli Mu , Lingli Han , Tao Liu . Quantum Chemical Calculation Study on the E2 Elimination Reaction of Halohydrocarbon: Designing a Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 68-75. doi: 10.12461/PKU.DXHX202404057
3. [3]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
4. [4]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
5. [5]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
6. [6]
  Xuefei Zhao , Xuhong Hu , Zhenhua Jia . 理论与计算化学在傅-克烷基化反应教学中的应用. University Chemistry, 2025, 40(8): 360-367. doi: 10.12461/PKU.DXHX202410008
7. [7]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
8. [8]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
9. [9]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
10. [10]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
11. [11]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
12. [12]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028
13. [13]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
14. [14]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
15. [15]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
16. [16]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
17. [17]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
18. [18]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
19. [19]
  Yaqin Zheng , Lian Zhuo , Meng Li , Chunying Rong . Enhancing Understanding of the Electronic Effect of Substituents on Benzene Rings Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 193-198. doi: 10.12461/PKU.DXHX202406119
20. [20]
  Jiabo Huang , Quanxin Li , Zhongyan Cao , Li Dang , Shaofei Ni . Elucidating the Mechanism of Beckmann Rearrangement Reaction Using Quantum Chemical Calculations. University Chemistry, 2025, 40(3): 153-159. doi: 10.12461/PKU.DXHX202405172

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(2053)
HTML views(888)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142