Citation: Zhang Ping, Peng Peng, Hou Bingbing, Ma Huiting, Zhai Cuiping. Studies on the Interactions of Glucose and Inositol with Ascorbic Acid[J]. Chemistry, ;2018, 81(3): 258-266. shu

Studies on the Interactions of Glucose and Inositol with Ascorbic Acid

Institute of Fine Chemical and Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004

Corresponding author: Zhai Cuiping, zhaicuiping@henu.edu.cn
Received Date: 19 October 2017
Accepted Date: 12 December 2017

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The interactions of glucose and inositol respectively with ascorbic acid (AA) were studied by electrochemistry, density functional theory methods and atoms in molecules analysis. The electrochemical results of the two mixed systems in aqueous solution and phosphate buffer saline (PBS) solution showed that the hydrogen atoms on the enediol of AA can form hydrogen bonds with the oxygen atoms on hydroxyl of glucose/inositol, making the electro-oxidation reaction of AA more difficult, which is further confirmed by quantum chemical calculation.
- Ascorbic acid,
- Glucose,
- Inositol,
- Interaction,
- Electrochemistry,
- Quantum chemical calculations
1. [1]
  J Du, J J Cullen, G R Buettner. Biochim. Biophys. Acta, 2012, 1826(2):443~457.
2. [2]
  S J Padayatty, A Katz, Y H Wang et al. J. Am. Coll. Nutr., 2003, 22(1):18~35.
3. [3]
  I F Hu, T Kuwana. Anal. Chem., 1986, 58(14):3235~3239.
4. [4]
  J Rozgaité, A Pocius, J Kuly. J. Electroanal. Chem., 1983, 154(1-2):121~128.
5. [5]
  Y M Chen, H Li. J. Phys. Chem. A, 2010, 114(43):11719~11724.
6. [6]
  I B Afanasev, V V Grabovetskii, N S Kuprianova. J. Chem. Soc. Perk. Transac., 1987, (3):281~285.
7. [7]
  Y Dimitrova. Spectrochim. Acta A, 2006, 63(2):427~437.
8. [8]
9. [9]
  P Li, Y Z Zhai, W H Wang et al. Struct. Chem., 2011, 22(4):783~793.
10. [10]
  E A Kazoyan, A M Terzyan, S A Markaryan. Russ. J. Phys. Chem. A, 2011, 85(4):612~616.
11. [11]
  N Niazazari, A L Zatikyan, S A Markarian. Spectrochim. Acta A, 2013, 110:217~225.
12. [12]
  D Martín-Yerga, J Carrasco-Rodríguez, J L G Fierro et al. Electrochim. Acta, 2017, 229:102~111.
13. [13]
  S Sharma, M Goodarzi, J Delanghe et al. Appl. Spectrosc., 2014, 68(4):398~405.
14. [14]
  G M Steil, K Rebrin, J Mastrototaro et al. Diabetes Technol. The., 2003, 5(1):27~31.
15. [15]
  A I Gopalan, N Muthuchamy, S Komathi et al. Biosens. Bioelectron., 2016, 84:53~63.
16. [16]
  C P Zhai, F Sun, P Zhang et al. J. Mol. Liq., 2016, 223:420~426.
17. [17]
  M Rahimi-Nasrabadi, F Mizani, M Hosseini et al. Spectrochim. Acta A, 2017, 186:82~88.
18. [18]
  E Fisher, S V McLennan, H Tada et al. Diabetes, 1991, 40(3):371~376.
19. [19]
  J J Li, H Q An, J Zhu et al. Sens. Actuat. B, 2016, 235:663~669.
20. [20]
  P K Banipal, M Sharma, N Aggarwal et al. J. Chem. Thermodyn., 2016, 102:322~332.
21. [21]
22. [22]
  S P Jengathe, S S Dhondge, L J Paliwal et al. J. Chem. Thermodyn., 2015, 87:78~87.
23. [23]
24. [24]
  M J Frisch, G W Trucks, H B Schlegel et al. Gaussian 09, Revision D.01; Gaussian, Inc.:Wallingford, CT, 2009.
25. [25]
26. [26]
  T Matsui, Y Kitagawa, M Okumura et al. J. Phys. Chem. A, 2015, 119(2):369~376.
27. [27]
28. [28]
29. [29]
30. [30]
  R N Singh, V Baboo, P Rawat et al. Spectrochim. Acta A, 2012, 94:288~301.
31. [31]
  U Koch, P L A Popelier. J. Phys. Chem., 1995, 99(24):9747~9754.
32. [32]
  M Zahedi-Tabrizi, F Ektefa. Monatshefte für Chemie-Chemical Monthly, 2015, 146(11):1837~1843.
33. [33]
  I Rozas, I Alkorta, J Elguero. J. Am. Chem. Soc., 2000, 122:11154~11161.
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