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Citation: XU Feng, LI Chuang, JIA Shao-yang, WU Yang, ZHU Li-hua. Pd(OAc)2 and chloranil-catalyzed oxidation of low-concentration coal mine gases to methanol[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(02): 239-243. shu

Pd(OAc)2 and chloranil-catalyzed oxidation of low-concentration coal mine gases to methanol

  • 1.

    College of Safety Engineering, Heilongjiang University of Science and Technology, Harbin 150022, China

  • Corresponding author: XU Feng, 
  • Received Date: 18 September 2015
    Available Online: 26 November 2015

  • A self-made experimental system was used to study the catalytic oxidation of low-concentration coal mine gases to methanol in acetic acid solution.With Pd(OAc)2 as catalyst,addition of p-benzoquinone or chloranil in the reaction system provides a beneficial environment for activation of methane,and chloranil shows a more positive effect.Chloranil amount and reaction temperature and pressure are the key factors influencing the catalytic properties.The target product yield has a positive relationship with these three factors.CH3OH is formed from the reaction of generated H2O2 and CH4.CH3COOCH3 is generated via two routes;one is direct oxidation of Pd2+ and CH4,the other is esterification of CH3OH and CH3COOH.
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