Citation: LI Lei-lei, TIAN Hui-hui, HAN Yan-mei, LIU Yan, GAO Zhi-hua, HUANG Wei. Structure and property of AlOOH in CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(7): 830-836. shu

Structure and property of AlOOH in CO hydrogenation

Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: GAO Zhi-hua, gaozhihua@tyut.edu.cn
Received Date: 18 December 2015
Revised Date: 23 March 2016

Fund Project: Natural Science Foundation of Shanxi Province 2012011046-1The project was supported by the National Natural Science Foundation of China 21336006

Figures(6)

AlOOH were prepared by precipitation-hydrothermal method with different water-to-gel ratios, which were mixed with industrial methanol synthesis catalyst C302 and tested for CO hydrogenation in the fixed-bed reactor. The AlOOH samples were characterized by XRD, FT-IR, BET, NH₃-TPD-MS, TG-DTG and H₂-TPR. The results showed that the ratios of water-to-gel in the hydrothermal process had obvious influence on the preferred orientation, pore structure and surface acidity of AlOOH, leading to the different selectivity of higher alcohols and DME. When the ratio of water-to-gel was 2:1, AlOOH showed in (020) and (120) preferred orientation. Moreover, it had larger pore volume and proper ratio of weak acid sites to strong acid sites, the composite catalyst showed a relatively high selectivity of higher alcohols, which indicated that AlOOH favored the growth of carbon chains. This study provided a new way for synthesis of higher alcohols from syngas.
- AlOOH,
- syngas,
- higher alcohols,
- precipitation hydrothermal method,
- dimethyl ether
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