Citation: CHEN Jiao-jiao, CHEN Guan-yi, MA Wen-chao, MA Long-long, WANG Tie-jun, ZHANG Qi, LÜ Wei. Experimental study of aromatics production from catalytic cracking of bio-oil model compounds[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(2): 183-188. shu

Experimental study of aromatics production from catalytic cracking of bio-oil model compounds

1.
1. School of Environmental Science & Engineering, State Key Laboratory of Engines of Tianjin University, Tianjin University, Tianjin 300072, China;

Corresponding author: CHEN Guan-yi, MA Long-long,
Received Date: 16 August 2012
Available Online: 18 October 2012
Fund Project: 国家自然科学基金(51036006) (51036006) 国家高技术研究发展计划(863计划, 2012AA051801) (863计划, 2012AA051801) 中国博士后科学基金(2011M501347)。 (2011M501347)

Catalytic cracking experiments were performed for bio-oil model compounds (acetic acid, guaiacol, n-heptane and hexamethylene, etc) using HZSM-5 molecular sieve catalyst at 550℃, aiming to study the reaction mechanism and catalyst properties. The results show that the main product for catalytic cracking of n-heptane and hexamethylene is aromatics (53% and 91%, respectively in area). Catalytic cracking reaction occurs more easily for those oxygen-free model compounds. The aromatics content increase effectively (from 12% to 90% in area) with increasing addition of catalyst for acetic acid. The guaiacol structure is quite complex and the catalyst mainly removes its methoxy group. Increasing the weight of catalyst could lead to aromatics formation more easily.
- model compound,
- catalytic cracking,
- bio-oil,
- HZSM-5,
- aromatics
1. [1]
  [1] LU Q, LI W-Z, ZHU X-F. Overview of fuel properties of biomass fast pyrolysis oils[J]. Energy Convers Manage, 2009, 50(5): 1376-1383.
2. [2]
  [2] MOHAN D, PITTMAN C U Jr, STEELE P H. Pyrolysis of wood/biomass for bio-oil: A critical review[J]. Energy Fuels, 2006, 20(3): 848-889.
3. [3]
  [3] ZHANG Q, CHANG J, WANG T-J, XU Y. Review of biomass pyrolysis oil properties and upgrading research[J]. Energy Convers Manage, 2007, 48(1): 87-92.
4. [4]
  [4] 韩红睿, 张瑞芹, 徐兴敏, 刘永刚, 张长森. 生物油-甲醇催化重整制氢的氢产率及碳转化率的研究[J].可再生能源, 2012, 30(8): 69-73. (HAN Hong-rui, ZHANG Rui-qin, XU Xing-min, LIU Yong-gang, ZHANG Chang-shen. Study in the hydrogen yield and carbon conversion rate of bio-oil-methanol catalytic reforming[J]. Renewable Energy Resourses, 2012, 30(8): 69-73.)
5. [5]
  [5] 熊万明, 傅尧, 来大明, 郭庆祥. 酸性离子交换树脂催化酯化改质生物油的研究[J]. 高等学校化学学报, 2009, 30(9): 1754-1758. (XIONG Wan-ming, FU Yao, LAI Da-ming, GUO Qing-xiang. Upgrading of bio-oil via esterification catalysted with acidic ion-exchange resin[J]. Chemical Research in Chinese Universities, 2009, 30(9): 1754-1758.)
6. [6]
  [6] KASTNER J R, MILLER J, GELLER D P, LOCKLIN J, KEITH L H, JOHNSON T. Catalytic esterification of fatty acids using solid acid catalysts generated from biochar and activated carbon[J]. Catal Today, 2012, 109(1): 122-132.
7. [7]
  [7] GU Yue-ling, Yin Qiang-qian, Wang Shu-rong, Li Xin-bao, Guo Zuo-gang, Luo Zhong-yang. Experimental Study on the Physico-chemical Properties of Bio-oil and Diesel Emulsification[J]. Advanced Materials Research, 2012, 433-440, 94-99.
8. [8]
  [8] GRACA I, LOPES J M, RIBEIRO M F, CERQUEIRA H S, de ALMEIDA M B B. Catalytic cracking in the presence of guaiacol[J]. Appl Catal B, 2011, 101(3/4): 613-621.
9. [9]
  [9] 刘熠斌, 王洪刚, 杨朝合, 山红红. 催化裂化汽油二次反应过程中反应热的变化[J]. 化工学报, 2009, 60(2): 358-364. (LIU Yi-bin, WANG Hong-gang, YANG Chao-he, SHAN Hong-hong. Variation of reaction heat for secondary reaction of FCC gasoline[J]. Journal of Chemical Industry and Engineering(China), 2009, 60(2): 358-364.)
10. [10]
  [10] 王丽红, 贾管臣, 柏雪源, 易维明, 殷哲. 生物质热解生物油的成分分析[J]. 太阳能学报, 2009, 30(8): 1124-1128. (WANG Li-hong, JIA Guan-chen, BAI Xue-yuan, YI Wei-ming, YIN Zhe. Compositional analysis of bio-oil derived from pyrolysis of biomass[J]. Acta Energiae Solaris Sinica, 2009, 30(8): 1124-1128.)
11. [11]
  [11] 常胜, 赵增立, 张伟, 郑安庆, 吴文强, 李海滨. 不同种类生物油化学组成结构的对比研究[J]. 燃料化学学报, 2011, 39(10): 746-753. (CHANG Sheng, ZHAO Zeng-li, ZHANG Wei, ZHENG An-qing, WU Wen-qiang, LI Hai-bin. Comparison of chemical composition and structure of different kinds of bio-oils[J]. Journal of Fuel Chemistry and Technology, 2011, 39(10): 746-753.)
12. [12]
  [12] 卢学栋, 杨彩虹, 窦秀云, 李文彬, 王定珠. 直链烷烃在HZSM-5上裂解反应[J]. 石油学报(石油加工), 1990, 6(2): 10-18. (LU Xue-dong, YANG Cai-hong, DOU Xiu-yun, LI Wen-bin, WANG Ding-zhu. Catalytic cracking of n-alkanes over HZSM-5 zeolite[J]. Acta Petrolei Sinica (Petroleum Processing Section), 1990, 6(2): 10-18.)
13. [13]
  [13] 刘全杰, 方向晨, 贾立明, 徐会青. 正庚烷在HZSM-5沸石催化剂上芳构化反应研究[J]. 石油炼制与化工, 2009, 40(10): 1-3. (LIU Quan-jie, FANG Xiang-chen, JIA Li-ming, XU Hui-qing. Study on the n-heptane aromatization reaction over ZSM-5 zeolite catalysts[J]. Petroleum Processing and Petrochemicals, 2009, 40(10): 1-3.)
14. [14]
  [14] 王滨, 高强, 高建东, 闫亮, 王晓来, 索继栓. 高硅分子筛ZSM-23的合成及表征[J]. 分子催化, 2004, 18(4): 253-256. (WANG Bin, GAO Qiang, GAO Jian-dong, YAN Liang, WANG Xiao-lai, SUO Ji-shuan. Synthesis and characterization of ZSM-23 zeolite with high silica[J]. Journal of Molecular Catalysis (China),2004, 18(4): 253-256.)
1. [1]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
2. [2]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
3. [3]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
4. [4]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
5. [5]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
6. [6]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
7. [7]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
8. [8]
  Ying Xiong , Guangao Yu , Lin Wu , Qingwen Liu , Houjin Li , Shuanglian Cai , Zhanxiang Liu , Xingwen Sun , Yuan Zheng , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Jianrong Zhang , Shuyong Zhang . Basic Operations and Specification Suggestions for Determination of Physical Constants of Organic Compounds. University Chemistry, 2025, 40(5): 106-121. doi: 10.12461/PKU.DXHX202503079
9. [9]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
10. [10]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
11. [11]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
12. [12]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
13. [13]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
14. [14]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
15. [15]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
16. [16]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
17. [17]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
18. [18]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
19. [19]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
20. [20]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046

Get Citation

PDF

XML

Metrics

PDF Downloads(639)
Abstract views(2468)
HTML views(156)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142