Citation: HUO Wei, ZHOU Zhi-jie, WANG Yi-fei, YU Guang-suo, HUANG Bin, ZHANG Yu-zhu. Gasification reactivity of feed coal and residue from an industrial gasification plant[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(2): 151-156. shu

Gasification reactivity of feed coal and residue from an industrial gasification plant

  • Corresponding author: YU Guang-suo, 
  • Received Date: 24 May 2012
    Available Online: 26 July 2012

  • The gasification reactivity of raw coal, filter cake and the slag in demister from an industrial gasification plant was investigated with steam and carbon dioxide as the gasification agent. The initial structure and surface characteristic of the samples were analyzed by scanning electron microscope and adsorption apparatus. The results show that the gasification reactivity of the raw coal is better than that of the slag in demister, while the gasification reactivity of the slag is similar to or a bit better than that of filter cake, which is mainly attributed to the extraordinary difference of surface and internal structure of these three samples. As a result of different reaction mechanism with steam and CO2, the gasification reactivity of the samples with steam is about 3 times higher than that with CO2.
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    1. [1]

      [1] 于广锁, 牛苗任, 王亦飞, 梁钦锋, 于遵宏.气流床煤气化的技术现状和发展趋势[J].现代化工, 2004, 24(5): 23-26. (YU Guang-suo, NIU Miao-ren, WANG Yi-fei, LIANG Qin-feng, YU Zun-hong. Application status and development tendency of coal entrained-bed gasification[J]. Modern Chemical Industry, 2004, 24(5): 23-26.)

    2. [2]

      [2] 张林仙, 黄戒介, 房倚天, 王洋.中国无烟煤焦气化活性的研究-水蒸气与二氧化碳气化活性的比较[J]. 燃料化学学报, 2006, 34(3): 265-269. (ZHANG Lin-xian, HUANG Jie-jie, FANG Yi-tian, WANG Yang. Study on reactivity of Chinese anthracite chars gasification——Comparsion of reactivity between steam and CO2 gasification[J]. Journal of Fuel Chemistry and Technology, 2006, 34(3): 265-269.)

    3. [3]

      [3] KORA K, IDA S. Gasification reactivities of metallurgical cokes with carbon dioxide, steam and their mixture[J]. Fuel, 1980, 59(1): 59-63.

    4. [4]

      [4] 乌晓江, 张忠孝, 朴桂林, 小林信介, 森滋勝, 板谷義紀. 高灰熔点煤高温下煤焦CO2水蒸气气化反应特性的实验研究[J]. 中国电机工程学报, 2007, 27(32): 24-28. (WU Xiao-jiang, ZHANG Zhong-xiao, PIAO Gui-lin, KOBAYASHI Nobusuke, MORI Shigekatsu, ITATYA Yoshinori. Experimental study on gasification reaction characteristics of Chinese high ash fusion temperature coal with CO2 and steam at elevated temperature[J]. Proceedings of the CSEE, 2007, 27(32): 24-28.)

    5. [5]

      [5] AHMED II, GUPTA A K. Kinetics of woodchips char gasification with steam and carbon dioxide[J].Appl Energy, 2011, 88(5): 1613-1619.

    6. [6]

      [6] MATSUMOTO K, TAKENO K, ICHINOSE T, OGI T, NAKANISHI M. Gasification reaction kinetics on biomass char obtained as a by-product of gasification in an entrained-flow gasifier with steam and oxygen at 900~1000 ℃[J]. Fuel, 2009, 88(3): 519-527.

    7. [7]

      [7] 马银剑, 黄斌, 杨加义, 雍晓静. GSP干煤粉气化装置试车总结[J].化肥工业, 2011, 38(5): 61-66. (MA Yin-jian, HUANG Bin, YANG Jia-yi, YONG Xiao-jing. Sum-up of trail run of GSP dry pulverized coal gasification Unit[J]. Journal of the Chemical Fertilizer Industry, 2011, 38(5): 61-66.)

    8. [8]

      [8] FENG B, BHATIA S K. Variation of the pore structure of coal chars during gasification[J]. Carbon, 2003, 41(3): 507-523.

    9. [9]

      [9] 杨海平, 陈汉平, 鞠付栋, 王静, 王贤华, 张世红. 热解温度对神府煤热解与气化特性的影响[J]. 中国电机工程学报, 2008, 28(8): 40-45. (YANG Hai-ping, CHEN Han-ping, JU Fu-dong, WANG Jing, WANG Xian-hua, ZHANG Shi-hong. Influence of temperature on coal pyrolysis and char gasification[J]. Proceedings of the CSEE, 2008, 28(8): 40-45.)

    10. [10]

      [10] YE D P, AGNEW J B, ZHANG D K. Gasification of a South Australian low-rank coal with carbon dioxide and steam: Kinetics and reactivity studies[J]. Fuel, 1998, 77(11): 1209- 1219.

    11. [11]

      [11] EVERSON R C, NEOMAGUS H W J P, KASAINI H, NJAPHA D. Reaction kinetics of pulverized coal-chars derived from inertinite-rich coal discards: Gasification with carbon dioxide and steam[J]. Fuel, 2006, 85(7/8): 1076-1082.

    12. [12]

      [12] 楚希杰, 李文, 白宗庆, 李宝庆, 陈皓侃. 神华煤直接液化残渣水蒸气和CO2气化反应性研究[J]. 燃料化学学报, 2010, 38(1): 1-5. (CHU Xi-jie, LI Wen, BAI Zong-qin, LI Bao-qin, CHEN Hao-kan. Gasification reactivity of Shenhua direct liquefaction residue with steam and CO2[J]. Journal of Fuel Chemistry and Technology, 2010, 38(1): 1-5.)

    13. [13]

      [13] 李庆峰, 房倚天, 张建民, 王洋, 时铭显, 孙国纲. 石油焦水蒸气气化过程孔隙结构和气化速率的变化[J]. 燃料化学学报, 2004, 32(4): 435-439. (LI Qin-feng, FANG yi-tian, ZHANG Jian-min, WANG Yang, SHI Ming-xian, SUN Guo-gang. Changes of pore structure and and gasification activity during steam-gasification of petroleum coke[J]. Journal of Fuel Chemistry and Technology, 2004, 32(4): 435-439.)

    14. [14]

      [14] DUTTA S, WEN C, BELT R. Reactivity of coal and char:1 In carbon dioxide atmosphere[J]. Ind Eng Chem Press Des Dev, 1977, 16(1): 20-30.

    15. [15]

      [15] HURT R, SAROFIM A, LONGWELL J. The role of microporous surface area in the gasification of chars from a sub-bituminous coal[J]. Fuel, 1991, 70(9): 1079-1082.

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