Citation: LIU Heng, ZHOU Chen, ZHANG Yi-nan, KAN Qiu-bin. Facile preparation of hierarchically porous IM-5 zeolite with enhanced catalytic performance in methane aromatization[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(9): 1074-1081. shu

Facile preparation of hierarchically porous IM-5 zeolite with enhanced catalytic performance in methane aromatization

1.
Research Center for Nanotechnology, Changchun University of Science and Technology, Changchun 130022, China
2.
College of Chemistry, Jilin University, Changchun 130023, China

Corresponding author: LIU Heng, liuhengjlu@163.com
Received Date: 8 May 2017
Revised Date: 19 July 2017

Fund Project: This project was supported by Youth Fund of Changchun University of Science and Technology (XJJLG-2015-12)Youth Fund of Changchun University of Science and Technology XJJLG-2015-12

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A novel hierarchically porous IM-5-H zeolite material was prepared through one-step crystallization route by means of adjusting the synthesis parameters without introducing any secondary template.The hierarchical IM-5-H zeolite is quite different from the conventional IM-5-C in morphology, textural and acidic properties.After loading Mo, the Mo-IM-5-H catalyst exhibits high activity and stability in non-oxidative aromatization of methane, with a methane conversion of 13.1% and aromatics yield of 7.5%, owing to the mesopores in the IM-5-H zeolite crystals.This work provides a simple way to synthesize hierarchical IM-5 zeolite and expands the application of micro-mesoporous composite material in methane dehydroaromatization.
- hierarchical pore structure,
- IM-5,
- zeolite,
- methane aromatization
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1.
沈阳化工大学材料科学与工程学院沈阳 110142