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Citation: Yao Xuebin, Zheng Limin, Xin Xinquan, Jin Tongzheng. Studies on Solid State Reactions of Coordination Compounds LXⅧ.The Solid State Reaction of 2-Aminopyrimidine with Copper (Ⅱ) Compounds at Room Temperature[J]. Chinese Journal of Applied Chemistry, ;1994, 11(6): 7-11. shu

Studies on Solid State Reactions of Coordination Compounds LXⅧ.The Solid State Reaction of 2-Aminopyrimidine with Copper (Ⅱ) Compounds at Room Temperature

1.
1. State key Laboratory of Coordination Chemistry, Department of Chemistry, Nanjing University, Nanjing 210008;
2.
2. Center of Modern Analysis, Nanjing University

Received Date: 21 February 1994
Available Online: 16 May 1994
Fund Project:

The solid state reactions of 2-aminopyrimidine (AP) with CuCl₂·2H₂O,CuBr₂,CuSO₄·5H₂O and CuAc₂·H₂O at room or near room temperature result in the formation of three kinds of complexes with coordination ratio Cu/AP=1:2,1:1 and 2:1 respectively.The solid products were chracterized by elemental analysis,XRD,ICP,UV,ESR methods.The mechanism of this kind of reations and the effects of copper and the reagents were discussed.
- solid state reaction,
- aminopyrimidine,
- copper(Ⅱ)complex
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