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Citation: Sun Yingji, Li Shunyu, Wang Fuquan, Chen Yaguang, Qu Lunyu. Redox Properties of Tungstogermanate Isomers Trisubstituted by Transition Elements[J]. Chinese Journal of Applied Chemistry, ;1994, 44(5): 83-86. shu

Redox Properties of Tungstogermanate Isomers Trisubstituted by Transition Elements

1.
Department of Chemistry, Northeast Normal University, Changchun 130024

Received Date: 22 October 1993
Available Online: 24 January 1994
Fund Project:

systematic study on the redox property of tungstogermanate isomers α- and β-M_xH_y[GeW₉M(H₂O)₃O₃₇]·nH₂O M'=Bu₄N⁺,K⁺;M=Cr³⁺,Mn²⁺,Co²⁺,Ni²⁺,Cu²⁺) was carried out by polarography and voltam metry in aqueous solution.A redox mechanism was proposed and the effects of substituted elements and the structure of anions on the redox property were discussed.The oxidation abilities of the α- and β-isomers were compared.
- tungstogermanate heteropoly complex,
- transitiondement,
- substituted complex,
- redox property
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