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Citation: Yang Chuncai, Wang Huabin, Jing Xiabin, Han Xiaozu, Chen Tianlu, Wang Fosong, Zhang Guicai. Synthesis of Cross-Linked Second Order Nonlinear Optical Poled Polymer[J]. Chinese Journal of Applied Chemistry, ;1994, 44(5): 22-26. shu

Synthesis of Cross-Linked Second Order Nonlinear Optical Poled Polymer

1.
1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
2. Department of Chemistry, Jilin University of Technology, Changchun

Received Date: 25 November 1993
Available Online: 22 June 1994

The crosslinking reaction of glycidyl monoether of 4-[(p-nitrophenyl) azo]phenolwith biuret of hexamethylene diisocyanate has been carried out and investigated by DSC and FTIR techniques.A fully crosslinked nonlinear optical polymer was obtained in a short time,which has a good transparency and maximum absorption wavelength shorter than 400nm.The uniform films formed by spin coating of the THF solution onto transparent substrates were precured for 30 min at 85℃ before corona poling.The orientation and stability of the films were studied by UV-vis spectrum measurement.The orientation of the film decreased to 40% of the original in 4 days after poling for 1.5h at 85℃.However,no relaxation of thepoled film was observed in 4 days after poling and crosslinking for 1h at 140℃.
- rosslinked nonlinear optical polymer,
- glycidyl monoether,
- biuret
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Synthesis of Cross-Linked Second Order Nonlinear Optical Poled Polymer

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com