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Citation: Chen Yuanyin, Hong Liwu, Duan Heping, Lu Xueran. Etherification and Polycondensation of 3,19-Dihydfoxy-1-Thia-5,8,11,14,17-Pentaoxa-Cycloicosane[J]. Chinese Journal of Applied Chemistry, ;1994, 11(3): 45-48. shu

Etherification and Polycondensation of 3,19-Dihydfoxy-1-Thia-5,8,11,14,17-Pentaoxa-Cycloicosane

1.
Department of Chemistry, Wuhan University, Wuhan 430072

Received Date: 4 October 1993
Available Online: 6 January 1994
Fund Project:

Etherification of 3,19-dihydroxy-1-thia-5,8,11,14,17-pentaoxa-cycloicosane with a series of alkyl,alkenyl,and arylalkyl halides takes place smoothly in diglyme and in the presence of NaHas a base.Dihexyloxy,didodecyloxy,dihexyldecyloxy,dibenzyloxy,and diallyloxy thia -20-crown -6 were prepared via the etherification,and four monolariat thiacrovvn ethers were also obtained as by prodticts.A polyester with thiacrown ether moieties incorporated in main chain can be obtained easily by polycondensation of dihydroxy thiacrown ether with sticcinyl chloride in the presence of pyridine.
- crown ether,
- polymeric crown ether,
- lariat thiacrown ether,
- polyester,
- esterification,
- polycondensation,
- synthesis
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Etherification and Polycondensation of 3,19-Dihydfoxy-1-Thia-5,8,11,14,17-Pentaoxa-Cycloicosane

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com