Citation:
Yang Luqin, Yan Shiping, Bai Lingjun, Liao Daizheng, Jiang Zonghui, Wang Genglin, Shen Panwen. Synthesis,Characterization and Bioactivity of Some Bicopper Complexes[J]. Chinese Journal of Applied Chemistry,
;1994, 11(3): 11-15.
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Nine novel bicopper complexes of N,N,N',N",N"-pentabenzimidazolylmethyl diethylenetriamine were synthesized and characterized by IR,UV-vis,ESR and magneticsusceptibity measurements.Their catecholase and bioactivities were measured.There appeared an antiferromagnetic exchange interaction between copper ions within the complexes.The coordination bond Cu-N was partially covanlent.It was found for the first time that the compounds containing benzimidazole ligand haveantitumer activities in vitro and herbicidal and fungicidal activities as well.
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Keywords:
- bicopper complex,
- benzimidazole,
- bioactivity,
- ESR,
- magnetic property
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