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Citation: Chen Zhen. Influence of Mediators on the Electrooxidation of Cinnamic Alcoho[J]. Chinese Journal of Applied Chemistry, ;1994, 11(1): 33-37. shu

Influence of Mediators on the Electrooxidation of Cinnamic Alcoho

Chen Zhen

1.
Experimental Center of Fujian Normal University, Fuzhou 350007

Received Date: 20 February 1993
Available Online: 7 June 1993
Fund Project:

Lead dioxide and manganese dioxide were used as mediator for indirect oxidation of cinnarnic alcohol on solid polymer electrolyte(SPE)composite electrode prepared by depositing a porous platnium layer on Nafion. When MnO₂ was used, cinnamic aldehyde was the main product of oxidatiorl with current efficieny up to 80%。In the case of PBO₂ a further oxidatinn of aldehvde to cinnamic acid and an obvious decrease of reaction selectivity on the electrode were observed.
- solid polynler electrolyte,
- cinnamic alcohol,
- electrooxidation,
- manganese dioxide,
- lead dioxide
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