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Citation: Xu Jinghua, Gong Yuqiu, Huang Xian. Studies on the Aromatic Ring Stacking Interaction of the Cu(Ⅱ)-Bipyridyl-Phenylcarboxylic Acid System by Extraction Method[J]. Chinese Journal of Applied Chemistry, ;1996, 13(1): 107-108. shu

Studies on the Aromatic Ring Stacking Interaction of the Cu(Ⅱ)-Bipyridyl-Phenylcarboxylic Acid System by Extraction Method

1.
Department of Chemistry, Hangzhou University, Hangzhou 310028

Received Date: 19 June 1995
Available Online: 25 September 1995
Fund Project:

The stacking interactions of aromatic rings in the Cu²⁺-bpy-PCA^- system(bpy=2,2'-bipyridyl,PCA=phenylcarboxylic acid) have been studied by extraction method in perchloric acid medium.The content of the stacked isomers of the extracted species[Cu(bPy)(PCA)(H₂O)]⁺ increases in the order:Bz^- - - -.The composition of complexes has been determined by slope method and elemental analysis.
- aromatic ring stacking interaction,
- copper,
- bipyridyl,
- phenylcarboxylic acid
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