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Citation: Zhang Congyun, Fang Tianru, Qiu Lingwei, Wang Fusong, Liu Peiyan. Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids[J]. Chinese Journal of Applied Chemistry, ;1996, 13(1): 1-5. shu

Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids

1.
1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
2. Department of Chemistry, The Northeast Normal University, Changchun 130022

Received Date: 7 June 1995
Available Online: 24 August 1995
Fund Project:

The solubility and colloidal properties of 2-acrylamidoalkanesulfonic acids were found to vary markedly with the alkyl length.Due to the existence of a chiral carbon,the peaks of methylene protons adjacent to it clearly split on the ¹H NMR spectra.The polymerization kinetics and colloidal properties of 2-acrylamidohexadecane sulfonic acid in water/dioxane mixed solvents were investigated.It is found that both the polymerization rate and the relative molecular mass of the resultant polymer have a minimum value when water/dioxane volume ratio is in the range of 1~1/2.The critical micelle concentration increases with the content of dioxane in the mixed solvent, and no apparent micelle formation is observed when water/dioxane volume ratio is 1/2~1/4.
- amphiphilic monomer,
- acrylamidoalkanesulfonic acid,
- solubility,
- critical micelle concentration,
- NMR,
- polymerization characteristics
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Water-Soluble and Amphiphilic Polymers 18. Amphiphilic Monomers of 2-Acrylamidoalkanesulfonic Acids

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com