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Citation: Cui Tong, Fu Chengguang. Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride[J]. Chinese Journal of Applied Chemistry, ;1996, 13(5): 97-99. shu

Derivatization of Amines with Phthalimidyl Benzene Sulphonyl Chloride

Cui Tong ¹ ,
Fu Chengguang ²

1.
1. Department of Food Science, Hebei Agriculture University, Baoding 071000;
2.
2. Research Centre of Physical and Chemical Analysis, Hebei University, Baoding 071000

Received Date: 25 December 1995
Available Online: 16 May 1996

The kinetic study showed that the water content has an important effect on the hydrolysis rate of phthalimidyl benzene sulphonyl chloride(Phisyl-Cl). The PH of the reaction medium should be higher than 8.0 and 9.0 for derivatization with primary and secondary amines respectively. The hydrolysis of PhisyI-Cl is inhibited by adding solid NaHCO₃ instead of its saturated solution to the medium to promote derivatization.
- phthalimidylbenzene sulphonyl chloride,
- amine,
- derivatizing reagent,
- derivatization
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