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Citation: Wang Xuesong, Zhang Baowen, Cao Yi. Sensitized Photoisomerization of a Norbornadiene Derivative in Aqueous Solution[J]. Chinese Journal of Applied Chemistry, ;1996, 13(5): 17-20. shu

Sensitized Photoisomerization of a Norbornadiene Derivative in Aqueous Solution

1.
Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing 100101

Received Date: 5 December 1995
Available Online: 4 May 1996
Fund Project:

In an aqueous solution and under the sensitization of acridine yellow(AY) or acridine orange(AO), the photoisomerization of bicyclo[2.2.1] hepta-2, 5-diene-2, 3-dicarboxylic acid(N) was investigated. The quantum yields of sensitized photoisomerizations for AY and AO are 0.33 and 0.31, respectively. Since the reaction medium is water which is safe and inexpensive, the sensitizers can harvest sunlight effectively and the preparation of water-soluble norbornadiene derivative is very easy, this photo reaction system is promising for solar energy storage. A mechanism involving electron transfer was proposed from the analysis of fluorescence quenching and thermodynamic discussion.
- bicyclo-heptadiene-dicarboxylic acid,
- acridine yellow,
- acridine orange,
- photoinduced valence isomerization,
- photoinduced electron transfer
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