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Citation: Zhang Youjin, He Qun, Xie Fuxin, Xu Zhiqiang, Ni Shisheng. Synthesis and Characterization of 5, 12-diphenyl-7, 14-dimethyl-1, 4, 8, 11-tetraazacyclotetradecane-N-acetic Acid and Its Cu(Ⅱ)、Ni(Ⅱ) Complexes[J]. Chinese Journal of Applied Chemistry, ;1996, 13(4): 104-106. shu

Synthesis and Characterization of 5, 12-diphenyl-7, 14-dimethyl-1, 4, 8, 11-tetraazacyclotetradecane-N-acetic Acid and Its Cu(Ⅱ)、Ni(Ⅱ) Complexes

1.
1. Department of Processing and Technology, Hefei Institute of Economics and Technology, Hefei 230052;
2.
2. Department of Chemistry, Anhui University, Hefei 230052

Received Date: 26 November 1995
Available Online: 8 April 1996
Fund Project:

A novel 14 membered N-acetic acid substituted tetraazamacrocyclic ligand, 5,12-diphenyl-7,14-dimethyl-l,4,8,11-tetraazacyclotetradecane-N-acetic acid (HL) has been synthesized in dry methanol by the interaction of 5, 12-diphenyl-7, 14-dimethyl-1,4,8,11-tetraazacyclotetradecane with bromoacetic acid. Its Cu (Ⅱ) and Ni(Ⅱ) complexes have also been prepared. The ligand and the complexes have been characterized by elemental analysis. IR, ¹H NMR,MS,UV-Vis spectra and conductivity measurements.
- tetraazacyclotetradecane-N-acetic acid,
- complex,
- synthesis,
- characterization
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