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Citation: Yan Cuiwei, Liao Daizheng. Synthesis,Magnetism and Antibacterial Activity of Binuclear Copper(Ⅱ) and Cobalt(Ⅱ) Complexes[J]. Chinese Journal of Applied Chemistry, ;1996, 13(3): 60-64. shu

Synthesis,Magnetism and Antibacterial Activity of Binuclear Copper(Ⅱ) and Cobalt(Ⅱ) Complexes

Yan Cuiwei ¹ ,
² ,
Liao Daizheng ³

1.
1. Department of Biology, Qufu Normal University, Qufu, Qufu 273165;
2.
2. Department of Chemistry, Qufu Normal University, Qufu 273165;
3.
3. Department of Chemistry, Nankai University, Tianjin

Received Date: 6 October 1995
Available Online: 18 December 1995
Fund Project:

Four new binuclear complexes,[Cu₂(IPHTA)(phen)₄](ClO₄)₂(1),[Cu₂(IPHTA)(tmen)₄](ClO₄)₂·H₂O(2),[Co₂(IPHTA)(phen)₄](ClO₄)₂(3)and[Co₂(IPHTA)(tmen)₄](ClO₄)₂(4)(IPHTA,phen and tmen denote isophthalato dianion; 1,10-phenanthroline and N,N,N',N'-tetramethylethlenediamine respectively)were synthesized and characterized by elemental analysis,IR,electronic spectra,conductivity and variable temperature magnetic susceptibility measurements.Based on the Heisenberg model, the exchange integral,J,was found to be 2.30 cm^-1for(1),3.82 cm^-1for(2),8.09 cm^-1 for(3)and 8.20 cm^-1for(4),indicating that a weak ferromagnetic spin exchange interaction occurs between the two metal ions.The biological activities of the complexes were also tested.
- μ-isophthalate,
- binuclear complex,
- long-range magnetic interaction,
- antibacterial activity
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