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Citation: Liu Shuxiang, Tian Laijin, Tian Junlian, Bi Siwei, Gao Enqing, Cao Peisen, Pan Feng. Stability of Ternary Mixed Ligand Complexes of N-Salicylideneaminio Acid and α-Amino Acid with Nickel(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;1996, 13(3): 50-54. shu

Stability of Ternary Mixed Ligand Complexes of N-Salicylideneaminio Acid and α-Amino Acid with Nickel(Ⅱ)

1.
Department of Chemistry, Qufu Normal University, Qufu 273165

Received Date: 6 October 1995
Available Online: 1 February 1996
Fund Project:

The dissociation constants of N-salicylideneamino acids(Sal:A)and stability contants of binary complexes of Ni(Ⅰ)-salicylideneamino acid and Ni(Ⅱ)-α-amino acid and ternary mixed ligand complexes of Ni(Ⅱ)-N-salicylideneamino acid(ligand A)-α-amino acid (ligand B)at(25±0.1)℃ and in the presence of 0.1mol/dm³ KNO₃ have been determined by pH method.The a-amino acids(Aa)used were glycine(Gly),L-serine(Ser),L-valine (Val),L-leucine(Leu),L-isoleucine(Iso)and L-proline(Pro).It was found that the linear free energy relationship(LFER)exists nicely between the following parameter pairs logβ₁₂₀ and pK₂^A,logβ₁₀₂ and pK₂^B,logβ₁₁₁ andp pK₂^A,logβ₁₁₁ and pK₂^B.The △logK was used to characterize the stability of ternary complexes related to the stability of parent binary complexes. The hydrophobic ligand-ligand interaction in the Ni(Sal:P)(P denotes phenylalanine)was studied.
- nickel(Ⅱ),
- linear free energy relationship,
- Schiff base,
- hydrophobic ligancl-ligand interaction
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