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Citation: Huang Jingqin, Tian He, Xiao Yanwen, Yang Zhenhua, Chen Wenqi. Synthesis and Properties of Photocurable Oligoester Acrylourethane Resins[J]. Chinese Journal of Applied Chemistry, ;1996, 13(2): 98-100. shu

Synthesis and Properties of Photocurable Oligoester Acrylourethane Resins

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 18 August 1995
Available Online: 27 November 1995

Oligoesters were prepared by the reaction of adipic acid with dibasic alcohols, such as glycol, propanedio1-1,2, diglycol and triglycol. The oligoesters reacted with hexamethylene-diisocyanate and glycol acrylate to give photocurable oligoester acrylourethane resins. The resins were characterized by elemental analysis, IR and ¹H NMR spectra. These resins are in the solid state or semi-solid state with specific gravity d₄²⁰1.18, bulk viscosity (at 38℃) 28500 MPa· s, pH=5.5, content of hydroxyl group 0.3%, photocuring speed<0.3 s, excellent gloss and levelling. They are used as a main component of printing ink.
- photocurable resin,
- oligoester,
- acrylourethane,
- synthesis
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