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Citation: Li Jing, Song Wei, Dou Bosheng. Selective Oxidation of Propane over Bismuth Vanadomolybdate Catalysts[J]. Chinese Journal of Applied Chemistry, ;1996, 13(2): 88-90. shu

Selective Oxidation of Propane over Bismuth Vanadomolybdate Catalysts

1.
Changchun Institute of Aplied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 4 July 1995
Available Online: 6 November 1995
Fund Project:

We have investigated the catalytic properties of scheelite-type oxide Bi_1-x/3V_1-x-MoxO₄ in the selective oxidation of propane to acrolein.When x is 0.45, the catalyst Bi_0.85V_0.55Mo_0.45O₄ shows good catalytic effect; the selectivity for acrolein is 23% at 54% conversion of propane. Monovalent silver promoter markedly improves catalytic performance of the bismuth vanadomolybdate Bi_0.85V_0.55Mo_0.45O₄. Under the optimum reaction condition. the catalyst Ag_0.01Bi_0.85V_0.54Mo_0.45O₄ shows much better catalytic performance with the selectivity for acrolein being 32% at 52% conversion of propane.
- propane,
- selective oxidation,
- bismuth vanadomolybdate,
- promoter,
- acrolein
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