Citation:
Zhang Hongfang, Mo Zhishen, Na Hui, Wu Zhongwen. Transformation of Tg and Tm for PEEKK-PEBEKK Copolymers with Various Biphenyl Content[J]. Chinese Journal of Applied Chemistry,
;1996, 13(2): 57-60.
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Transformational behaviour of Tg and Tm for PEEKK-PEBEKK copolymers with various biphenyl content was studied by using DSC. Results revealed that the glass transition temperature Tg for the copolymers gradually increased with increasing biphenyl content nB. The melting points Tm of the copolymers obviously depended on nB. Tm value was minimum when nB=0.35. Heat behaviour of the copolymers could be markedly changed by heat treatment. Behaviour of double melting peak for the copolymer resulted from the crystal melting and the recrystallization was also studied.
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