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Citation: He Zhengjie, Li Zhengming, Wang Honggen, Wang Ruji. Synthesis, Structure and Biological Activity of Novel Silicon-containing Carbamates[J]. Chinese Journal of Applied Chemistry, ;1996, 13(2): 1-6. shu

Synthesis, Structure and Biological Activity of Novel Silicon-containing Carbamates

1.
1. Elemento-Organic Chemistry Institute, Nankai University, Tianjin 300071;
2.
2. Central Laboralory, Nankai University, Tianjin 300071

Received Date: 4 July 1995
Available Online: 30 October 1995
Fund Project:

A series of new silicon-containing carbamate derivatives 3 have been prepared from reaction of 1-methylthio-ethylideneamino-methyl carbamate (Methomyl) 1 with thionyl chloride. Their structures were confirmed by ¹H NMR,elemental analysis,IR and MS. The crystal structure of compound 3a was determined by X-ray diffraction method.The bioassay results showed that compound 3 have a high insecticidal activity against mosquito,armyworm, European corn borer, flour beetle and cowpea aphid and a substantial improvement in acute mammalian safety toward male and female mice when compared to that of parent Methomyl.
- carbamates,
- silicon derivative,
- biological activity
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