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Citation: Zhang Li, Liao Shijian, Xu Yun, Zhang Wenming, Yu Daorong. Reduction of Nitro Compounds Using Nanometric Sodium Hydride Promoted by Transition Metal Salt[J]. Chinese Journal of Applied Chemistry, ;1997, 14(6): 18-21. shu

Reduction of Nitro Compounds Using Nanometric Sodium Hydride Promoted by Transition Metal Salt

1.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Received Date: 11 March 1997
Available Online: 7 August 1997
Fund Project:

The reduction of nitro compounds by the nanometric sodium hydride (NaH^*) in the presence of a transition metal salt has been studied. The results show that the reductive activity of the nanometric NaH is greatly enhanced by the addition of a transition metal salt, so that a conversion of nitrobenzene over 90% can be achieved in a short time. It is found that nickel salt is the best promoter for the aniline formation, then is the manganese salt. Different hydrides (LiH^*, NaH^*, KH^*) exhibit different selectivities towards reaction pro-ducts in the reduction of nitrobenzene. The results of reduction of several nitro compounds reveal that the combination of NaH^* and a nickel salt is an effective reagent for the reduction of aromatic nitro compounds to their corresponding amines.
- nanometric sodium hydride,
- transition metal salt,
- nitro compound reduction
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