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Citation: Zhong Qiling, Huang Qunjian, Liu Fengming, Yao Jianlin, Wang Zhongquan, Xiong Lihua, Tian Zhongqun. Raman Spectroscopic Study on Coadsorption of 1-Allyl-2-thiourea with Various Electrolyte Anions at Silver Electrodes[J]. Chinese Journal of Applied Chemistry, ;1997, 14(6): 13-17. shu

Raman Spectroscopic Study on Coadsorption of 1-Allyl-2-thiourea with Various Electrolyte Anions at Silver Electrodes

1.
1. Department of Chemistry, Jiangxi Normal University, Nanchang;
2.
2. State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, Institute of Physical Chemistry, Xiamen University, Xiamen 361005

Received Date: 31 March 1997
Available Online: 12 August 1997
Fund Project:

Using surface enhanced Raman scattering (SERS) and time-resolved surface enhanced Raman scattering (TRSERS) spectroscopies, the electrochemical coadsorption of 1-allyl-2-thiourea(ATU) with one or two kinds of eletrolyte anions at sliver electrodes in perchloric acid, sulphuric acid, nitric acid medium respectively has been studied. The orientation of ATU on the surface was proposed. The results indicate that these anions can be coadsorbed on the electrode, induced by the protonated amino groups of ATU surface. The order of the coadsorption with ATU was found to be:ClO₄^- > SO₄^2- > NO₃^-.
- allylthiourea,
- electrolyte anion,
- coadsorption,
- silver electrode,
- SERS
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