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Citation: He Junxiang, Zhou Jincheng. Electrochemical Epoxidation of Cyclohexene[J]. Chinese Journal of Applied Chemistry, ;1997, 14(5): 107-109. shu

Electrochemical Epoxidation of Cyclohexene

1.
Department of Chemistry, Wenzhou Normal College, Wenzhou 325003

Received Date: 22 November 1996
Available Online: 5 June 1997

Epoxycyclohexane was prepared in yield of 86.2% by electrochemical epoxidation of cyclohexene at Ti/SnO₂+Sb₂O₃/PbO₂ anode, at current density 0.4 A/dm² in H₂O-NaBr-MeCN medium (V_H₂O:V_MeCN=4:1, C_NaBr=0.04 mol/dm³). Ti/SnO₂+Sb₂O₃/PbO₂ anode showed a more excellent catalytic activity than Ti/RuO₂ anode.
- electrochemical epoxidation,
- epoxycyclohexane,
- cyclohexene,
- titanium anode
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